Sadržaj elemenata u tragu u urbanom zemljištu Šapca i procena ekološkog rizika
DOI:
https://doi.org/10.5937/zasmat2102083AKljučne reči:
urbano zemljište, elementi u tragu, zagađenje, ŠabacApstrakt
Ovaj rad se bavi procenom kontaminacije urbanog zemljišta u Šapcu elementima u tragu. Sa lokacija tri gradska parka u urbanoj zoni sakupljeno je ukupno 32 uzorka površinskog sloja zemljišta (do 10 cm dubine). Pseudototalne koncentracije sedam elemenata: bakra (Cu), olova (Pb), kobalta (Co), nikla (Ni), mangana (Mn), kadmijuma (Cd) i hroma (Cr) određene su u uzorcima posle digestije u smesi kiselina (HCl/HNO3), korišćenjem atomske apsorpcione spektrofotometrije. Zastupljenost elemenata u analiziranim uzorcima zemljišta je bila: Mn>> Pb > Cr > Ni > Cu > Co > Cd. Korelaciona analiza je pokazala dobru korelisanost parova elemenata Cu - Pb, Cu - Cd i Pb - Cd, dok su klasterskom analizom izdvojene dve glavne grupe elemenata. Prva grupa je uključivala Pb, Cd i Cu, što je ukazivalo da ovi elementi potiču iz antropogenih izvora, dok su preostali elementi verovatno geogenog porekla. Na osnovu dobijenih rezultata izvršena je procena nivoa kontaminacije zemljišta elementima u tragu, kao i procena ekološkog rizika. Srednje vrednosti faktora kontaminacije ukazuju da je zemljište sa sve tri ispitivane lokacije kontaminirano Pb i Cd. Od svih elemenata najveći potencijalni ekološki rizik ima Cd.Reference
(2010) Uredba o programu sistematskog praćenja kvaliteta zemljišta, indikatori za ocenu rizika od degradacije i zagađenja i metodologiji za izradu remedijacionih programa.Službeni glasnik Republike Srbije, br. 88
(2020) Agents classified by the IARC. Lyon: International Agency for Research on Cancer (IARC), Monographs; Volumes 1-128. https://monographs. iarc.fr/list-of-classifications
(2009) Izveštaj o stanju zemljišta u Republici Srbiji. Beograd: Ministarstvo životne sredine i prostornog planiranja-Agencija za zaštitu životne sredine
Adriano, D.C. (2001) Trace elements in terrestrial environments: biogeochemistry, bioavailability and risks of metals. New York: Springer-Verlag
https://doi.org/10.1007/978-0-387-21510-5
Ali, M.H., Mustafa, A.A.A., El-Sheikh, A.A. (2016) Geochemistry and spatial distribution of selected heavy metals in surface soil of Sohag, Egypt: A multivariate statistical and GIS approach.Environmental Earth Sciences, 75(18): 1257-1271
https://doi.org/10.1007/s12665-016-6047-x
Alloway, B.J. (1995) Trace metals in soil. London: Chapman & Hall
https://doi.org/10.1007/978-94-011-1344-1
Alloway, B.J. (1990) Heavy metals in soils. London: Blackie
Begum, A., Ramaiah, M., Harikrishna,, Khan, I., Veena, K. (2009) Analysis of heavy metals concentration in soil and litchens from various localities of Hosur road, Bangalore, India.Journal of Chemistry, 6(1): 13-22
https://doi.org/10.1155/2009/943695
Biswas, S., Dey, R., Mukherjee, S., Banerjee, P.C. (2013) Bioleaching of nickel and cobalt from lateritic chromite overburden using the culture filtrate of Aspergillus Niger.Applied Biochemistry and Biotechnology, 170(7): 1547-1559
https://doi.org/10.1007/s12010-013-0289-9
Buszewski, B., Jastrebska, A., Kowalkowski, T., Gorna-Binkul, A. (2000) Monitoring of selected heavy metals uptake by plants and soils in the area of Torun, Poland.Polish J. of Environ. Stud, 9(6): 511-515
Chen, T.-.B., Zheng, Y.-.M., Lei, M., Huang, Z.-.C., Wu, H.-.T., Chen, H., Fan, K.-.K., Yu, K., Wu, X., Tian, Q.-.Z. (2005) Assessment of heavy metal pollution in surface soils of urban parks in Beijing, China.Chemosphere, 60(4): 542-551
https://doi.org/10.1016/j.chemosphere.2004.12.072
Davis, A.P., Shokouhian, M., Ni, S. (2001) Loading estimates of lead, copper, cadmium, and zinc in urban runoff from specific sources.Chemosphere, 44(5): 997-1009
https://doi.org/10.1016/S0045-6535(00)00561-0
Davydova, S. (2005) Heavy metals as toxicants in big cities.Microchemical Journal, 79(1-2): 133-136
https://doi.org/10.1016/j.microc.2004.06.010
de Pereira, P.A.P., Lopes, W.A., Carvalho, L.S., da Rocha, G.O., de Bahia, N.C., Loyola, J., Quiterio, S.L., Escaleira, V., Arbilla, G., de Andrade, J.B. (2007) Atmospheric concentrations and dry deposition fluxes of particulate trace metals in Salvador, Bahia, Brazil.Atmospheric Environment, 41: 7837-7850
https://doi.org/10.1016/j.atmosenv.2007.06.013
Đurkić, T., Grujić, S., Laušević, M. (2015) Metode analize zagađujućih materija. Beograd: Univerzitet u Beogradu - Tehnološko-metalurški fakultet
Enamorado-Báez, S.M., Gómez-Guzmán, J.M., Chamizo, E., Abril, J.M. (2015) Levels of 25 trace elements in high-volume air filter samples from Seville (2001-2002): Sources, enrichment factors and temporal variations.Atmospheric Research, 155: 118-129
https://doi.org/10.1016/j.atmosres.2014.12.005
Escarré, J., Lefèbvre, C., Raboyeau, S., Dossantos, A., Gruber, W., Cleyet, M.J.C., Frérot, H., Noret, N., Mahieu, S., Collin, C., van Oort, F. (2011) Heavy metal concentration survey in soils and plants of the Les Malines mining district (southern France): Implications for soil restoration.Water, Air, & Soil Pollution, 216(1-4): 485-504
https://doi.org/10.1007/s11270-010-0547-1
Fujiwara, F., Rebagliati, R.J., Dawidowski, L., Gómez, D., Polla, G., Pereyra, V., Smichowski, P. (2011) Spatial and chemical patterns of size fractionated road dust collected in a megacitiy.Atmospheric Environment, 45(8): 1497-1505
https://doi.org/10.1016/j.atmosenv.2010.12.053
Galić, Z., Pilipović, A., Orlović, S., Klašnja, B., Ivanišević, P., Kebert, M. (2008) Characteristics of soils in Novi Sad parks and their heavy metal load.Topola, br. 181-182, str. 11-20
Giusti, L. (2011) Heavy metals in urban soils of Bristol (UK): Initial screening for contaminated land.Journal of Soils and Sediments, 11: 1385-1398
https://doi.org/10.1007/s11368-011-0434-4
Gope, M., Masto, R.E., George, J., Hoque, R.R., Balachandran, S. (2017) Bioavailability and health risk of some potentially toxic elements (Cd, Cu, Pb and Zn) in street dust of Asansol, India.Ecotoxicology and Environmental Safety, 138: 231-241
https://doi.org/10.1016/j.ecoenv.2017.01.008
Gope, M., Masto, R.E., George, J., Balachandran, S. (2018) Tracing source, distribution and health risk of potentially harmful elements (PHEs) in street dust of Durgapur, India.Ecotoxicology and Environmental Safety, 154: 280-293
https://doi.org/10.1016/j.ecoenv.2018.02.042
Hakanson, L. (1980) An ecological risk index for aquatic pollution control: A sedimentological approach.Water Research, 14(8): 975-1001
https://doi.org/10.1016/0043-1354(80)90143-8
Hjortenkrans, D.S.T., Bergbäck, B.G., Haggerud, A.V. (1995) Metal emissions from brake linings and tires: Case studies of Stockholm, Sweden 1995/1998 and 2005.Environ. Sci. Technol, 41: 5224-5230
https://doi.org/10.1021/es070198o
Imperato, M., Adamo, P., Naimo, D., Arienzo, M., Stanzione, D., Violante, P. (2003) Spatial distribution of heavy metals in urban soils of Naples city (Italy).Environmental Pollution, 124(2): 247-256
https://doi.org/10.1016/S0269-7491(02)00478-5
Iqbal, J., Shah, M.H. (2011) Distribution, correlation and risk assessment of selected metals in urban soils from Islamabad, Pakistan.Journal of Hazardous Materials, 192(2): 887-898
https://doi.org/10.1016/j.jhazmat.2011.05.105
Jaradat, Q.M., Momani, K.A. (1999) Contamination of roadside soil, plants and air with heavy metals in Jordan: A comparative study.Turk. J. Chem, 23: 209-220
Johansson, L., Westerlund, L. (2001) Energy savings in indoor swimming-pools: Comparison between different heat-recovery systems.Applied Energy, 70(4): 281-303
https://doi.org/10.1016/S0306-2619(01)00043-5
Kabata-Pendias, A., Mukherjee, A.B. (2007) Trace elements from soil to human. Berlin-Heidelberg-New York: Springer, Part II -Biogeochemistry of Trace Elements; p.257-378
https://doi.org/10.1007/978-3-540-32714-1
Kelepertzis, E. (2014) Accumulation of heavy metals in agricultural soils of Mediterranean: Insights from Argolida basin, Peloponnese, Greece.Geoderma, 221-222: 82-90
https://doi.org/10.1016/j.geoderma.2014.01.007
Kuoppamäki, K., Setälä, H., Rantalainen, A.L., Kotze, J.D. (2014) Urban snow indicates pollution originating from road traffic.Environmental Pollution, 195: 56-63
https://doi.org/10.1016/j.envpol.2014.08.019
Kuzmanoski, M.M., Todorović, M.N., Urošević-Aničić, M.P., Rajšić, S.F. (2014) Heavy metal content of soil in urban parks of Belgrade.Hemijska industrija, vol. 68, br. 5, str. 643-651
https://doi.org/10.2298/HEMIND131105001K
Ledoux, F., Kfoury, A., Delmaire, G., Roussel, G., El, Z.A., Courcot, D. (2017) Contributions of local and regional anthropogenic sources of metals in PM 2.5 at an urban site in northern France.Chemosphere, 181: 713-724
https://doi.org/10.1016/j.chemosphere.2017.04.128
López, J.M., Callén, M.S., Murillo, R., García, T., Navarro, M.V., de la Cruz, M.T., Mastral, A.M. (2005) Levels of selected metals in ambient air PM10 in an urban site of Zaragoza (Spain).Environmental Research, 99(1): 58-67
https://doi.org/10.1016/j.envres.2005.01.007
Madrid, L., Díaz-Barrientos, E., Reinoso, R., Madrid, F. (2004) Metals in urban soils of Sevilla: Seasonal changes and relations with other soil components and plant contents.European Journal of Soil Science, 55(2): 209-217
https://doi.org/10.1046/j.1365-2389.2004.00589.x
Madrid, L., Diaz-Barrientos, E., Madrid, F. (2002) Distribution of heavy metal contents of urban soils in parks of Seville.Chemosphere, 49(10): 1301-1308
https://doi.org/10.1016/S0045-6535(02)00530-1
Manta, D.S., Angelone, M., Bellanca, A., Neri, R., Sprovieri, M. (2002) Heavy metals in urban soils: a case study from the city of Palermo (Sicily), Italy.Science of The Total Environment, 300(1-3): 229-243
https://doi.org/10.1016/S0048-9697(02)00273-5
Marjanović, M.D., Vukčević, M.M., Antonović, D.G., Dimitrijević, S.I., Jovanović, Đ.M., Matavulj, M.N., Ristić, M.Đ. (2009) Heavy metals concentration in soils from parks and green areas in Belgrade.Journal of the Serbian Chemical Society, vol. 74, br. 6, str. 697-706
https://doi.org/10.2298/JSC0906697M
Markert, S.G.B. (1998) Ecotoxicology: Ecological fundamentals, chemiexposure, and biological effects. John Wiley & Sons
Mielke, H.W., Gonzales, C.R., Smith, M.K., Mielke, P.W. (1999) The urban environment and children's health: Soils as an integrator of lead, zinc, and cadmium in New Orleans, Louisiana, U.S.A.Environmental Research, 81(2): 117-129
https://doi.org/10.1006/enrs.1999.3966
Mihailović, A., Budinski-Petković, Lj., Popov, S., Ninkov, J., Vasin, J., Ralević, N.M., Vučinić-Vasić, M. (2015) Spatial distribution of metals in urban soil of Novi Sad, Serbia: GIS based approach.Journal of Geochemical Exploration, 150: 104-114
https://doi.org/10.1016/j.gexplo.2014.12.017
National Research Council (2003) Bioavalability of contaminants in soils and sediments: Processes, tools and applications. Washington, DC: National Academy Press
Nicholas, H.C., Rashed, M.B. (1990) An integrated budget for selected pollutants for a major rural highwa.Sci. Total Environ, 93: 375-384
https://doi.org/10.1016/0048-9697(90)90128-H
o'Connor J.D., Ok, Y.S., Tsang, D.C.W., Liu, A., Hou, D.D. (2019) Assessment of sources of heavy metals in soil and dust at children's playgrounds in Beijing using GIS and multivariate statistical analysis.Environment International, 124: 320-328
https://doi.org/10.1016/j.envint.2019.01.024
Onder, S., Dursun, S., Gezgin, S., Demirbas, A. (2007) Determination of heavy metal pollution in grass and soil of city centre green areas: Konya, Turkey.Polish J. of Environ. Stud, 16(1): 145-154
Pacyna, J.M., Pacyna, E.G. (2001) An assessment of global and regional emissions of trace metals to the atmosphere from anthropogenic sources worldwide.Environmental Reviews, 9(4): 269-298
https://doi.org/10.1139/a01-012
Rajšić, S., Mijić, Z., Tasić, M., Radenković, M., Joksić, J. (2008) Evaluation of the levels and sources of trace elements in urban particulate matter.Environmental Chemistry Letters, 6(2): 95-100
https://doi.org/10.1007/s10311-007-0115-0
Roje, V., Orešković, M., Rončević, J., Bakšić, D., Pernar, N., Perković, I. (2018) Assessment of the trace element distribution in soils in the parks of the city of Zagreb (Croatia).Environmental Monitoring and Assessment, 190(3): 121-142
https://doi.org/10.1007/s10661-018-6487-8
Romić, M., Romić, D. (2003) Heavy metals distribution in agricultural topsoils in urban area.Environmental Geology, 43(7): 795-805
https://doi.org/10.1007/s00254-002-0694-9
Sánchez-Camazano, M., Sánchez-Martín, M.J., Lorenzo, L.F. (1994) Lead and cadmium in soils and vegetables from urban gardens of Salamanca (Spain).Science of The Total Environment, 146-147: 163-168
https://doi.org/10.1016/0048-9697(94)90233-X
Sieghardt, M., Mursch-Radlgruber, E., Paoletti, E., Couenberg, E., Dimitrakopoulus, A., Rego, F., Hatzistathis, A., Barfeod, R.T. (2005) The abiotic urban environment: Impact of urban growing conditions on urban vegetation. in: Urban Forests and Trees, Springer-Verlag, 281-323
https://doi.org/10.1007/3-540-27684-X_12
Singh, A.K., Cameotra, S.S. (2013) Efficiency of lipopeptide biosurfactants in removal of petroleum hydrocarbons and heavy metals from contaminated soil.Environmental Science and Pollution Research, 20(10): 7367-7376
https://doi.org/10.1007/s11356-013-1752-4
Steinnes, E. (1987) Impact of long-range atmospheric transport of heavy metals to the terrestrial environment in Norway. in: Hutchinson T. C.; Meema K.M. [ed.] Lead, Mercury, Cadmium and Arsenic in the Environment, John Wiley & Sons, 107-117
Sun, Y.B., Zhou, Q.X., Xie, X.K., Liu, R. (2010) Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China.Journal of Hazardous Materials, 174(1-3): 455-462
https://doi.org/10.1016/j.jhazmat.2009.09.074
Teng, Y.G., Ni, S., Wang, J.G., Niu, L. (2009) Geochemical baseline of trace elements in the sediment in Dexing area, South China.Environmental Geology, 57(7): 1649-1660
https://doi.org/10.1007/s00254-008-1446-2
US Government (2001) Control of emissions of hazardous air pollutants from mobile sources.Final rule. Fed. Regis, 66: 80-86
Wang, Y., Yang, Z.F., Shen, Z.Y., Tang, Z.W., Niu, J.F., Gao, F. (2011) Assessment of heavy metals in sediments from a typical catchment of the Yangtze River, China.Environmental Monitoring and Assessment, 172(1-4): 407-417
https://doi.org/10.1007/s10661-010-1343-5
Weckwerth, G. (2001) Verification of traffic emitted aerosol components in the ambient air of Cologne (Germany).Atmospheric Environment, 35(32): 5525-5536
https://doi.org/10.1016/S1352-2310(01)00234-5
Werkenthin, M., Kluge, B., Wessolek, G. (2014) Metals in European roadside soils and soil solution: A review.Environmental Pollution, 189: 98-110
https://doi.org/10.1016/j.envpol.2014.02.025
Winther, M., Slentø, E. (2010) Heavy metal emissions for Danish road transport. Aarhus, Denmark: Aarhus University - National Environmental Research Institute
Yan, X., Zhang, F., Zeng, C., Zhang, M., Devkota, L.P., Yao, T. (2012) Relationship between heavy metal concentrations in soils and grasses of roadside farmland in Nepal.International Journal of Environmental Research and Public Health, 9(9): 3209-3226
https://doi.org/10.3390/ijerph9093209
Yazdi, M., Behzad, N. (2009) Heavy metal contamination and distribution in the parks city of Islam Shahr, SW Tehran, Iran.Open Environmental Pollution & Toxicology Journal, 1(1): 49-53
https://doi.org/10.2174/1876397900901010049
Yuan, G., Sun, T., Han, P., Li, J., Lang, X. (2014) Source identification and ecological risk assessment of heavy metals in topsoil using environmental geochemical mapping: Typical urban renewal area in Beijing, China.Journal of Geochemical Exploration, 136: 40-47
https://doi.org/10.1016/j.gexplo.2013.10.002
Zhang, G.L., Yang, F.G., Zhao, W.J., Zhao, Y.G., Yang, J.L., Gong, Z.T. (2007) Historical change of soil Pb content and Pb isotope signatures of the cultural layers in urban Nanjing.Catena, 69: 51-56
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