Decreasing of water absorptiveness of paper by coating nanofibrillated cellulose films

Jovana Milanović; Irena Živković; Milena Milošević; Mirjana Kostić

doi:10.5937/zasmat2103180M

Autori

Jovana Milanović University of Belgrade, Faculty of Technology and Metallurgy, Innovation Center, Serbia Autor
Irena Živković University of Arts, Faculty of Applied Arts, Serbia Autor
Milena Milošević University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM, Serbia Autor
Mirjana Kostić University of Belgrade, Faculty of Technology and Metallurgy, Serbia Autor

DOI:

https://doi.org/10.5937/zasmat2103180M

Ključne reči:

nanofibrilisani celulozni filmovi, TEMPO-oksidisana celuloza, papir, sposobnost upijanja vode, ugao kvašenja, optička svojstva, morfologija površine

Apstrakt

Nanofibrilisani filmovi na bazi TEMPO-oksidisanog pamučnog lintersa upotrebljeni su za smanjenje hidrofilnih svojstava papira. U tu svrhu su vodene disperzije nanofibrilisane celuloze različitog sastava: 1 i 3% nanofibrilisane celuloze, do 13% CaCO3 i/ili Al(OH)3, do 20% propan-1,2diol (glikol) i do 21% TEMPO-oksidisanih vlakana pamuka, nanošene na model papire, bez dodatka adheziva. Polazni i modifikovani model papiri sa oslojenim filmovima na bazi nanofibrilisane celuloze karakterisani su sa aspekta sposobnosti upijanja vode po COBB metodi i određen je ugao kvašenja. Izgled i hemijski sastav površine papira karakterisani su skenirajućom elektronskom mikroskopijom (SEM) i infracrvenom spektroskopijom sa Furijeovom transformacijom (ATR-FTIR). Pored toga, primenom odgovarajućih standarda određena su optička svojstva polaznog i modifikovanih papira (CIE lab koordinate, refleksija, CIE stepen beline). Zavisno od sastava disperzija, svi model papiri pokazali su određeno smanjenje sposobnosti upijanja vode, bez promena optičkih svojstava i morfologije površine papira u odnosu na nemodifikovani papir.

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