Synthesis of two supramolecular coordination polymers and electrochemical evaluation of their corrosion inhibition performance on corrosion of carbon steel in acidic medium

Waseef Essam El; Safaa Eldin H. Etaiw

doi:10.5937/zasmat2104316F

Autori

Waseef Essam El Mansoura University, Faculty of Science, Department of Chemistry, Mansoura, Egypt Autor
Safaa Eldin H. Etaiw Tanta University, Faculty of Science, Department of Chemistry, Tanta, Egypt Autor

DOI:

https://doi.org/10.5937/zasmat2104316F

Ključne reči:

supramolekularni koordinacioni polimeri, kisela korozija, ugljenični čelik, Henrijeva izoterma, EIS

Apstrakt

Efekat SCPs-[CuII(en)2] [CuI (CN)2]2. H2O (SCP1) i {[H2DAB] [Cu4(CN)6].2H2O} (SCP2) kao inhibitori korozije za ugljenični čelik (CS) proučavani su u 1,0 M rastvoru HCl. Kako se doza sintetizovanog inhibitora povećava, produktivnost inhibicije (%n) raste dostižu i 90,3% i 89,9% pri dozi od 21x10-6M za SCP2 i SCP1, respektivno. Ovaj rezultat je dokazan gubitkom mase (ML) ispitivanim na tri različitih temperatura 25-35-450C, dok su potenciodinamička polarizacija (PP), spektroskopija elektrohemijske impedanse (EIS) i tehnika elektrohemijske modulacije frekvencije (EFM) testirani na 25°C. Sintetizovani inhibitori adsorbovani na površini CS fizički dozvoljavaju i Henrijevu izotermu. Rezultati su pokazali da su sintetisani inhibitori odlični i da je njihov (%n) značajno povećan povećanjem doze i smanjen povećanjem temperature. Polarizacione krive su pokazale da sintetisani inhibitori deluju kao mešoviti tip. Termodinamički parametri su izračunati i diskutovani. Zaštita je potvrđena stvaranjem tankog filma inhibitora taloženog na površini CS.

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