Adsorption and inhibitive impact of 5-[4-(dimethylamino) benzylidene]-1,3-dimethylbarbituric acid on carbon steel corrosion in molar hydrochloric acid solution

El Khalek Khaled M. Abdel; Kamal Shalabi; Mohamed A. Ismail; El Aziz Abd S. Fouda

doi:10.5937/zasmat2203238A

Autori

El Khalek Khaled M. Abdel Mansoura University, Faculty of Science, Department of Chemistry, Mansoura, Egypt Autor
Kamal Shalabi Mansoura University, Faculty of Science, Department of Chemistry, Mansoura, Egypt Autor
Mohamed A. Ismail Mansoura University, Faculty of Science, Department of Chemistry, Mansoura, Egypt Autor
El Aziz Abd S. Fouda Mansoura University, Faculty of Science, Department of Chemistry, Mansoura, Egypt Autor

DOI:

https://doi.org/10.5937/zasmat2203238A

Ključne reči:

ugljenični čelik, HCl, EFM, EIS, derivat 5-ariliden barbiturne kiseline

Apstrakt

IInhibicijski uticaj ekološki prihvatljive 5-[4-(dimetilamino) benziliden -1, -dimetil barbiturne kiseline u 1M HCl na koroziju ugljeničnog čelika je ispitan pomoću metoda gubitka težine (VL), potenciodinamičke polarizacije (PP), elektrohemijske impedansne spektroskopije (EIS) i testova elektrohemijske frekvencijske modulacije (EFM). Postignuti rezultati pokazuju da je ispitivano jedinjenje odličan inhibitor i da se njegova efikasnost inhibicije (%IE) povećava povećanjem koncentracije i smanjuje povećanjem temperature. Adsorpcija 5-ariliden barbiturne kiseline na površini ugljeničnog čelika prati Langmuirovu izotermu. Proces adsorpcije ispitivanog jedinjenja je spontan i smatra se hemisorpcionim. PP krive su otkrile da je derivat 5-ariliden barbiturne kiseline inhibitor mešovitog tipa. Štaviše, rezultati EIS-a su potvrdili adsorpciju ispitivanog jedinjenja na površini ugljeničnog čelika kroz povećanje otpora prenosa naelektrisanja (Rct). IE% ovog inhibitora dostigao je 86,9% pri koncentraciji 21×10-6 M prema PP metodi. Konačno, eksperimentalni i teorijski rezultati su u dobroj harmoniji.

Reference

Abd, E.R.S.S., Hassan, H., M., Amin, A. (2003) The corrosion inhibition study of sodium dodecyl benzene sulphonate to aluminum and its alloys in 1.0 M HCl solution.Mater. Chem. Phys, 78: 337-348

https://doi.org/10.1016/S0254-0584(01)00602-2

Abd, E.R.S.S., Hassan, H.H., Amin, M.A. (2001) Corrosion inhibition of aluminum by 1,1(lauryl amido)propyl ammonium chloride in HCl solution.Materials Chemistry and Physics, 70(1): 64-72

https://doi.org/10.1016/S0254-0584(00)00468-5

Abdallah, Y.M., Shalabi, K., Bayoumy, N.M. (2018) Eco-friendly synthesis, biological activity and evaluation of some new pyridopyrimidinone derivatives as corrosion inhibitors for API 5L X52 carbon steel in 5% sulfamic acid medium.Journal of Molecular Structure, 1171: 658-671

https://doi.org/10.1016/j.molstruc.2018.06.045

Agrawal, Y.K., Talati, J.D., Shah, M.D., Desai, M.N., Shah, N.K. (2003) Schiff bases of ethylenediamine as corrosion inhibitors of zinc in sulphuric acid.Corrosion Science, 46(3), 633-651

https://doi.org/10.1016/S0010-938X(03)00174-4

Aljourani, J., Raeissi, K., Golozar, M.A. (2009) Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution.Corrosion Science, 51(8): 1836-1843

https://doi.org/10.1016/j.corsci.2009.05.011

Ansari, K.R., Sudheer, B., Singh, A., Quraishi, M.A. (2015) Some pyrimidine derivatives as corrosion inhibitor for mild steel in hydrochloric acid.Journal of Dispersion Science and Technology, 36: 908-917

https://doi.org/10.1080/01932691.2014.938349

Arab, S.T., Noor, E.A. (1993) Inhibition of acid corrosion of steel by some s-alkylisothiouronium iodides.Corrosion, 49(2): 122-129

https://doi.org/10.5006/1.3299206

Aramaki, K., Hagiwara, M., Nishihara, H. (1987) The synergistic effect of anions and the ammonium cation on the inhibition of iron corrosion in acid solution.Corrosion Science, 27(5): 487-497

https://doi.org/10.1016/0010-938X(87)90092-8

Ashassisorkhabi, H., Shaabani, B., Seifzadeh, D. (2005) Effect of some pyrimidinic Shciff bases on the corrosion of mild steel in hydrochloric acid solution.Electrochimica Acta, 50(16-17): 3446-3452

https://doi.org/10.1016/j.electacta.2004.12.019

Ashassi-Sorkhabi, H., Ghalebsaz-Jeddi, N. (2005) Inhibition effect of polyethylene glycol on the corrosion of carbon steel in sulphuric acid.Materials Chemistry and Physics, 92(2-3): 480-486

https://doi.org/10.1016/j.matchemphys.2005.01.059

Awad, H.S., Abdel, G.S. (2005) Mechanism of inhibition of iron corrosion in hydrochloric acid by pyrimidine and series of its derivatives.Anti-Corrosion Methods and Materials, 52(6): 328-336

https://doi.org/10.1108/00035590510624668

Banerjee, G., Malhotra, S.N. (1992) Contribution to adsorption of aromatic amines on mild steel surface from HCl solutions by impedance, UV, and Raman spectroscopy.Corrosion, 48(1): 10-15

https://doi.org/10.5006/1.3315912

Bayol, E., Kayakırılmaz, K., Erbil, M. (2007) The inhibitive effect of hexamethylenetetramine on the acid corrosion of steel.Materials Chemistry and Physics, 104(1): 74-82

https://doi.org/10.1016/j.matchemphys.2007.02.073

Benali, O., Larabi, L., Traisnel, M., Gengembre, L., Harek, Y. (2007) Electrochemical, theoretical and XPS studies of 2-mercapto-1-methylimidazole adsorption on carbon steel in 1M HClO4.Applied Surface Science, 253(14): 6130-6139

https://doi.org/10.1016/j.apsusc.2007.01.075

Bosch, R.W., Hubrecht, J., Bogaerts, W.F., Syrett, B.C. (2001) Electrochemical frequency modulation: A new electrochemical technique for online corrosion monitoring.Corrosion, 57(1): 60-70

https://doi.org/10.5006/1.3290331

Brown, D.J. (1994) The Pyrimidines. New York, NY: Interscience

Damaskin, B.B., Petrii, O.A., Batrakov, V.V. (1971) Adsorption of organic compounds on electrodes. in: Adsorption of Organic compounds on Electrodes, New York: Plenum Press

https://doi.org/10.1007/978-1-4615-8192-5

Ebenso, E.E., Ekpe, U.J., Ita, B.I., Offiong, O.E., Ibok, U.J. (1999) Effect of molecular structure on the efficiency of amides and thiosemicarbazones used for corrosion inhibition of mild steel in hydrochloric acid.Materials Chemistry and Physics, 60(1): 79-90

https://doi.org/10.1016/S0254-0584(99)00074-7

Elachouri, M., Hajji, M.S., Kertit, S., Essassi, E.M., Salem, M., Coudert, R. (1995) Some surfactants in the series of 2-(alkyldimethylammonio) alkanol bromides as inhibitors of the corrosion of iron in acid chloride solution.Corrosion Science, 37(3): 381-389

https://doi.org/10.1016/0010-938X(94)00134-R

Elewady, G.Y. (2008) Pyrimidine derivatives as corrosion inhibitors for carbon-steel in 2M hydrochloric acid solution.Int J. Electrochem. Sci, 3: 1149-1161

https://doi.org/10.1016/S1452-3981(23)15511-8

Epelboin, I., Keddam, M., Takenouti, H. (1972) Use of impedance measurements for the determination of the instant rate of metal corrosion.Journal of Applied Electrochemistry, 2(1): 71-79

https://doi.org/10.1007/BF00615194

Fan, H.B., Fu, C.Y., Wang, H.L., Guo, X.P., Zheng, J.S. (2002) Inhibition of corrosion of mild steel by sodium n,n-diethyl dithiocarbamate in hydrochloric acid solution.Br. Corros. J, 37, 122-125

https://doi.org/10.1179/000705902225004383

Feng, Y., Chen, S., Guo, W., Zhang, Y., Liu, G. (2007) Inhibition of iron corrosion by 5,10,15,20-tetraphenylporphyrin and 5,10,15,20-tetra-(4-chlorophenyl)porphyrin adlayers in 0.5M H2SO4 solutions.Journal of Electroanalytical Chemistry, 602(1): 115-122

https://doi.org/10.1016/j.jelechem.2006.12.016

Fouda, A.S., Ibrahim, H., Rashawn, S., El-Hossiany, A., Ahmed, R.M. (2018) Expired drug (pantoprazole sodium) as a corrosion inhibitor for high Carbon steel in hydrochloric acid solution.Int. J. Electrochem. Sci, 13: 6327-6346

https://doi.org/10.20964/2018.07.33

Fouda, A.S., Eissa, M., El-Hossiany, A. (2018) Ciprofloxacin as eco-friendly corrosion inhibitor for Carbon steel in hydrochloric acid solution.Int. J. Electrochem. Sci., 13, 11096-11112

https://doi.org/10.20964/2018.11.86

Fouda, A.S., Abd, E.S.A., El-Hossiany, A., Ibrahim, A. (2019) Corrosion protection of stainless steel 201 in acidic media using novel hydrazine derivatives as corrosion inhibitors.International Journal of Electrochemical Science, 14: 2187-2207

https://doi.org/10.20964/2019.03.15

https://doi.org/10.20964/2019.07.65

Fouda, A.S., Abd, E.M.A., Sherif, M.H., El-Habab, A.T., El-Hossiany, A. (2020) Novel anionic 4-tert-octyl phenol ethoxylate phosphate surfactant as corrosion inhibitor for C-steel in acidic media.Protection of Metals and Physical Chemistry of Surfaces, 56(1): 189-201

https://doi.org/10.1134/S2070205120010086

Fouda, A.S., Abdel-Latif, E., Helal, H.M., El-Hossiany, A. (2021) Synthesis and characterization of some novel thiazole derivatives and their applications as corrosion inhibitors for zinc in 1 M hydrochloric acid solution.Russian Journal of Electrochemistry, 57(2): 159-171

https://doi.org/10.1134/S1023193521020105

Fouda, A.S., El-Mekabaty, A., Shaaban, I.E.I., El-Hossiany, A. (2021) Synthesis and biological evaluation of novel thiophene derivatives as green inhibitors for aluminum corrosion in acidic media.Protection of Metals and Physical Chemistry of Surfaces, 57(5): 1060-1075

https://doi.org/10.1134/S2070205121050075

Fouda, A.S., Ahmed, R.E., El-Hossiany, A. (2021) Chemical, electrochemical and quantum chemical studies for famotidine drug as a safe corrosion inhibitor for a-brass in HCl solution.Protection of Metals and Physical Chemistry of Surfaces, 57(2) 398-411

https://doi.org/10.1134/S207020512101010X

Fouda, A.S., Abdallah, Y.M., Nabil, D. (2014) Dimethyl pyrimidine derivative as corrosion inhibitors for CS in hydrochloric acid solutions.Int. J. Innovat. Res. Sci. Eng. Technol, 3: 12965-12982

Gece, G., Bilgic, S. (2009) Quantum chemical study of some cyclic nitrogen compounds as corrosion inhibitors of steel in NaCl media.Corrosion Science, 51(8): 1876-1878

https://doi.org/10.1016/j.corsci.2009.04.003

Guo, R., Liu, T., Wei, X. (2002) Effects of SDS and some alcohols on the inhibition efficiency of corrosion for nickel.Colloids and Surfaces A: Physicochemical and Engineering Aspects, 209(1): 37-45

https://doi.org/10.1016/S0927-7757(02)00032-8

Hajjaji, N., Rico, I., Srhiri, A., Lattes, A., Soufiaoui, M., Ben, B.A. (1993) Effect of N-Alkylbetaines on the corrosion of Iron in 1 M HCl solution.Corrosion, 49(4): 326-334

https://doi.org/10.5006/1.3316057

Ismail, M.A., Al-Shihry, S., Arafa, R.K., El-Ayaan, U. (2013) Synthesis, antimicrobial activity and molecular modeling study of substituted 5-arylpyrimido.Journal of Enzyme Inhibition and Medicinal Chemistry, 28: 530-538

https://doi.org/10.3109/14756366.2011.654113

Jafari, H., Sayin, K. (2016) Sulfur containing compounds as corrosion inhibitors for mild steel in hydrochloric acid solution.Transactions of the Indian Institute of Metals, 69(3): 805-815

https://doi.org/10.1007/s12666-015-0556-2

Khaled, M.A., Ismail, M.A., El-Hossiany, A.A., Fouda, A.E.A.S. (2021) Novel pyrimidine-bichalcophene derivatives as corrosion inhibitors for copper in 1 M nitric acid solution.RSC Adv, 11: 25314-25333

https://doi.org/10.1039/D1RA03603C

Lahmidi, S., Elyoussfi, A., Dafali, A., Elmsellem, H., Sebbar, N.K., Ouasif, L., Jilalat, A.E., Mahi, B., Essassi, E.M., Abdel-Rahman, I., Hammouti, B. (2017) Corrosion inhibition of mild steel by two new 1,2,4-triazolo1,5-a.pyrimidine derivatives in 1 M HCl: Experimental and computational study.J. Mater. Environ. Sci, 8: 225-237

Lukovits, I., Bako, I., Shaban, A., Kalman, E. (1998) Polynomial model of the inhibition mechanism of thiourea derivatives.Electrochim. Acta, 43: 131-136

https://doi.org/10.1016/S0013-4686(97)00241-7

Luo, H., Guan, Y.C., Han, K.N. (1998) Inhibition of mild steel corrosion by sodium dodecyl benzene sulfonate and sodium oleate in acidic solutions.Corrosion, 54(8): 619-627

https://doi.org/10.5006/1.3287638

Macllwain, C. (1993) Activists now urge caution on approval of new AIDS drug.Nature, 365: 378-378

https://doi.org/10.1038/365378a0

Mahmoud, S.S., Ahmed, M.M. (2006) Corrosion inhibition of carbon steel using aminopyrimidine derivatives.Port. Electrochim. Acta, 24: 37-52

https://doi.org/10.4152/pea.200601037

Migahed, M., Azzam, E., Al-Sabagh, A. (2004) Corrosion inhibition of mild steel in 1 M sulfuric acid solution using anionic surfactant.Materials Chemistry and Physics, 85(2-3): 273-279

https://doi.org/10.1016/j.matchemphys.2003.12.027

Migahed, M.A., Azzam, E.M.S., Morsy, S.M.I. (2009) Electrochemical behaviour of carbon steel in acid chloride solution in the presence of dodecyl cysteine hydrochloride self-assembled on gold nanoparticles.Corrosion Science, 51(8): 1636-1644

https://doi.org/10.1016/j.corsci.2009.04.010

Moussa, M.N.H., El-Far, A.A., El-Shafei, A.A. (2007) The use of water-soluble hydrazones as inhibitors for the corrosion of C-steel in acidic medium.Materials Chemistry and Physics, 105(1): 105-113

https://doi.org/10.1016/j.matchemphys.2007.04.007

Mu, G.N., Zhao, T.P., Liu, M., Gu, T. (1996) Effect of metallic cations on corrosion inhibition of an anionic surfactant for mild steel.Corrosion, 52(11): 853-856

https://doi.org/10.5006/1.3292077

Noce, R.D., Fugivara, C.S., Barelli, N., Benedetti, A.V. (2003) Electrochemical studies of cu-al alloys in sulphate solutions with different ph.Portugaliae Electrochimica Acta, 21(2): 117-139

https://doi.org/10.4152/pea.200302117

Obot, I.B., Macdonald, D.D., Gasem, Z.M. (2015) Density functional theory (DFT) as a powerful tool for designing new organic corrosion inhibitors: Part 1: An overview.Corrosion Science, 99: 1-30

https://doi.org/10.1016/j.corsci.2015.01.037

Osman, M., Omar, A., Al-Sabagh, A. (1997) Corrosion inhibition of benzyl triethanol ammonium chloride and its ethoxylate on steel in sulphuric acid solution.Materials Chemistry and Physics, 50(3): 271-274

https://doi.org/10.1016/S0254-0584(97)01941-X

Palaniappan, N., Cole, I.S., Kuznetsov, A.E. (2020) Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl.RSC Advances, 10(19): 11426-11434

https://doi.org/10.1039/C9RA10702A

Parr, R.G., Donnelly, R.A., Levy, M., Palke, W.E. (1978) Electronegativity: The density functional viewpoint.Journal of Chemical Physics, 68(8): 3801-3807

https://doi.org/10.1063/1.436185

Quraishi, M.A., Ansari, F.A., Jamal, D. (2002) Thiourea derivatives as corrosion inhibitors for mild steel in formic acid.Mater.Chem. Phys, 77: 687-690

https://doi.org/10.1016/S0254-0584(02)00130-X

Raspini, I. A. (1993) Influence of sodium salts of organic acids as additives on localized corrosion of aluminum and its alloys.Corrosion, 49(10): 821-828

https://doi.org/10.5006/1.3316005

Samide, A. (2013) A pharmaceutical product as corrosion inhibitor for carbon steel in acidic environments.Journal of Environmental Science and Health, Part A, 48(2): 159-165

https://doi.org/10.1080/03601234.2012.716744

Schweinsberg, D.P., Nanayakkara, G.A., Steinert, D.A. (1988) The protective action of epoxy resins and curing agents-inhibitive effects on the aqueous acid corrosion of iron and steel.Corros. Sci, 28(1): 33-42

https://doi.org/10.1016/0010-938X(88)90004-2

Shettigar, S., Umesh, G., Poornesh, P., Manjunatha, K.B., Asiri, A.M. (2009) The third-order nonlinear optical properties of novel styryl dyes.Dyes and Pigments, 83(2): 207-210

https://doi.org/10.1016/j.dyepig.2009.04.009

Shi, D., Shi, J., Rong, S. (2010) A facile and clean synthesis of pyrimidine derivatives via three-component reaction in aqueous media.Chinese Journal of Chemistry, 28(5): 791-796

https://doi.org/10.1002/cjoc.201090148

Singh, D.D.N., Dey, A.K. (1993) Synergistic effects of inorganic and organic cations on inhibitive performance of propargyl alcohol on steel dissolution in boiling hydrochloric acid solution.Corrosion, 49(7): 594-600

https://doi.org/10.5006/1.3316090

Stanković, Z.D., Vuković, M. (1996) The influence of thiourea on kinetic parameters on the cathodic and anodic reaction at different metals in H2SO4 solution.Electrochimica Acta, 41(16): 2529-2535

https://doi.org/10.1016/0013-4686(96)00066-7

Stovanova, A.E., Skolova, E.I., Riacheva, S.N. (1997) The inhibition of mild steel corrosion in 1 M HCl in the presence of linear and cyclic thiocarbamidesEffect of concentration and temperature of the corrosion medium.Corros. Sci, 39: 1595-1604

https://doi.org/10.1016/S0010-938X(97)00063-2

Trabanelli, G. (1991) Whitney award lecture: Inhibitors: An old remedy for a new challenge.Corrosion, 47(6): 410-419

https://doi.org/10.5006/1.3585271

Vazquez, A.E., Silva, G.N., Beltrán, D.A., Pardavé, M.E.P., Romo, M.A.R., Hernández, H.H. (2011) Electrochemical impedance evaluation of uracil and thymine pyrimidine derivatives and its nucleosides compounds as a non-toxic corrosion inhibitors of steels in 1M HCl.ECS Trans, 36: 217-228

https://doi.org/10.1149/1.3660615

Villamil, R.F.V., Corio, P., Agostinho, S.M.L., Rubim, J.C. (1999) Effect of sodium dodecylsulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotriazole.Journal of Electroanalytical Chemistry, 472(2): 112-119

https://doi.org/10.1016/S0022-0728(99)00267-3

Zhao, T.P., Mu, G.N. (1999) The adsorption and corrosion inhibition of anion surfactants on aluminium surface in hydrochloric acid.Corrosion Science, 41(10): 1937-1944

https://doi.org/10.1016/S0010-938X(99)00029-3

Zucchi, F., Trabanelli, G., Brunoro, G. (1992) The influence of the chromium content on the inhibitive efficiency of some organic compounds.Corrosion Science, 33(7): 1135-1139

https://doi.org/10.1016/0010-938X(92)90167-2