Adsorption inhibitive properties of Rosmarinus officinalis L. on aluminium AA8011 alloy in 1.0M HCl

Paul A. Andoor; Kelechukwu B. Okeoma; Uchenna S. Mbamara

doi:10.5937/zasmat2302204A

Autori

Paul A. Andoor Federal University of Technology, Department of Physics, Owerri, Nigeria Autor
Kelechukwu B. Okeoma Federal University of Technology, Department of Physics, Owerri, Nigeria Autor
Uchenna S. Mbamara Federal University of Technology, Department of Physics, Owerri, Nigeria Autor

DOI:

https://doi.org/10.5937/zasmat2302204A

Ključne reči:

aluminijum, gubitak težine, korozija, Langmuir, magnetno polje

Apstrakt

Mehanizam adsorpcije Rosmarinus officinalis L. kao inhibitora korozije legure Al AA8801 u 1,0 M HCl proučavan je gravimetrijskom metodom i termodinamičkim studijama na 303, 313, 323 i 333 K. Koncentracije inhibitora su se kretale između 0 i 1000 mg/L. Rezultati pokazuju da se mehanizam adsorpcije Rosmarinus officinalis L. odvija putem fizisorpcije, generalno endotermne i praćena je rezultiraju im smanjenjem poremećaja. Efikasnost inhibitora je u velikoj meri opadala sa povećanjem temperature i smanjenjem koncentracije ekstrakta. Prisustvo spoljašnjeg magnetnog polja pojačalo je rastvaranje pasiviziraju ih Al2O3 filmova, čime je povećana brzina korozije.

Reference

Abdallah, M., Zaafarany, I., Fawzy, A., Radwan, M.A., Abdfattah, E. (2013) Inhibition of aluminum corrosion in hydrochloric.Corrosion, 22(3): 53-59

Andoor, P.A., Tech, B., Okeoma, K.B., Mbamara, U.S. (2021) Corrosion inhibition mechanism of rosemary leaf extract and effect of an external magnetic field on aluminium alloy.International Journal of Physical Sciences, 16(2): 79-95

https://doi.org/10.5897/IJPS2021.4945

Ating, E.I., Umoren, S.A., Udousoro, I.I., Ebenso, E.E., Udoh, A.P. (2010) Leaves extract of ananas sativumas green corrosion inhibitor for aluminium in hydrochloric acid solutions.Green Chemistry Letters and Reviews, 3(2): 61-68

https://doi.org/10.1080/17518250903505253

Beda, R.H., Niamien, P.M., Bilé, E., Trokourey, A. (2017) Inhibition of aluminium corrosion in 1.0M HCl by caffeine: Experimental and DFT studies.Adv. Chem, 1-10

https://doi.org/10.1155/2017/6975248

Chaubey, N., Singh, V.K., Quraishi, M.A. (2018) Papaya peel extract as potential corrosion inhibitor for aluminium alloy in 1 M HCl: Electrochemical and quantum chemical study.Ain Shams Engineering Journal, 9(4): 1131-1140

https://doi.org/10.1016/j.asej.2016.04.010

David, B.T. (2003) Corrosion of aluminum andits alloys. in: Handbook of Aluminum, CRC Press, book

Foo, K.Y., Hameed, B.H. (2010) Insights into the modeling of adsorption isotherm systems.Chemical Engineering Journal, 156(1): 2-10

https://doi.org/10.1016/j.cej.2009.09.013

Habtemariam, S. (2016) The therapeutic potential of rosemary (Rosmarinus officinalis) diterpenes for Alzheimer s disease, evidence-based complementary and alternative medicine. book

https://doi.org/10.1155/2016/2680409

Ituen, E., Akaranta, O., James, A. (2017) Evaluation of performance of corrosion inhibitors using adsorption isotherm models: An overview.Chem. Sci. Int. J, 18(1): 1-34

https://doi.org/10.9734/CSJI/2017/28976

John, W., Kelechi, D., Ugochukwu, J. (2018) Green inhibitor for corrosion of aluminium alloy AA8011A in acidic environment.IRJET, 5: 121-124

Khan, G., Newaz, K.M.S., Basirun, W.J., Ali, H.B.M., Faraj, F.L., Khan, G.M. (2015) Application of natural product extracts as green corrosion inhibitors for metals and alloys in acid pickling processes: A review.Int. J. Electrochem. Sci, 10(8): 6120-6134

https://doi.org/10.1016/S1452-3981(23)06707-X

Lowson, R.T. (1978) Aluminium corrosion studies: IV: Pitting corrosion.Australian Journal of Chemistry, 31(5): 943-943

https://doi.org/10.1071/CH9780943

Lyubchik, S., Lyubchik, A., Lygina, O., Lyubchik, S., Fonsec, I. (2011) Comparison of the thermodynamic parameters estimation for the adsorption process of the metals from liquid phase on activated carbons. IntechOpen, 4: 4-122

https://doi.org/10.5772/19514

Maghraby, A.A. (2009) Corrosion inhibition of aluminum in hydrochloric acid solution using potassium iodate inhibitor.The Open Corrosion Journal, 2(1): 189-196

https://doi.org/10.2174/1876503300902010189

Nardeli, J.V., Fugivara, C.S., Taryba, M., Pinto, E.R.P., Montemor, M.F., Benedetti, A.V. (2019) Tannin: A natural corrosion inhibitor for aluminum alloys.Progress in Organic Coatings, 135: 368-381

https://doi.org/10.1016/j.porgcoat.2019.05.035

Nwosu, O.O., Daodu, O., Ogbunude, B., Emelle, C., Nnanna, E.A., Emesi, J. (2022) Corrosion inhibition for mild steel in 0.5 M H 2 SO 4 solution using Achyranthes aspera L. leaf extract.African J. Pure Appl. Chem, 7(2): 56-60

Patni, N., Agarwal, S., Shah, P. (2013) Greener approach towards corrosion inhibition.Chinese Journal of Engineering, 4: 1-10

https://doi.org/10.1155/2013/784186

Rousan, A.A., Al-Rawashdeh, N.A.F. (2006) Magnetic field effects on inhibition of aluminium corrosion by cationic surfactant in acidic solution.Corrosion Engineering, Science and Technology, 41(3): 235-239

https://doi.org/10.1179/174327806X132150

Saha, P., Chowdhury, S. (2011) Insight into adsorption thermodynamics. in: Tadashi Mizutani [ed.] Thermodynamics, InTech

https://doi.org/10.5772/13474

Sangeetha, M., Rajendran, S., Sathiyabama, J., Krishnaveni, A. (2013) Inhibition of corrosion of aluminium and its alloys by extracts of green inhibitors.Portugaliae Electrochimica Acta, 31(1): 41-52

https://doi.org/10.4152/pea.201301041

Sukiman, N.L., i dr. (2012) Aluminium alloys: New trends in fabrication and applications. in: Zaki Ahmad [ed.] Alum. Alloy. -New Trends Fabr. Appl., book

Vadi, M., Moradi, N. (2011) Study of adsorption isotherms of acetamide and propionamide on carbon nanotube.Orient. J. Chem, 27(4): 1491-1495

Velázquez-González, M.A., Gonzalez-Rodriguez, J.G., Valladares-Cisneros, M.G., Hermoso-Diaz, I.A. (2014) Use of Rosmarinus officinalis as green corrosion inhibitor for carbon steel in acid medium.American Journal of Analytical Chemistry, 5(2): 55-64

https://doi.org/10.4236/ajac.2014.52009