The inhibition of mild steel corrosion by papaya and neem extracts
DOI:
https://doi.org/10.5937/zasmat2303274NKeywords:
corrosion inhibition, papaya, neem, plant extracts, mild steelAbstract
This study examined earlier research on using papaya and neem extracts as inhibitors to minimize the corrosion of mild steel in a variety of corrosive situations. The potential inhibitory characteristics of plant extracts to potentially replace the hitherto used, well-known inhibitors that are harmful to the people handling them as well as the environment, inspired several scholars to conduct corrosion inhibition tests on metals using plant extracts. The findings of earlier research demonstrated that the maximal inhibitory efficiency provided by neem leaf extract to prevent the degradation of carbon steel in a hydrochloric acid (1 M) medium was 97%, while 86% was observed for the protection in H2SO4 (1 M) solution. The extract from Carica papaya leaves was shown to have up to 83% maximum inhibitory efficacy for preventing mild steel corrosion in HCl (1 M). It has been revealed that when extract concentration increased, the rate of steel corrosion reduced. Additionally, papaya leaves' corrosion-inhibiting mechanism was said to occur mostly in the cathodic area. Both plant-leaf extracts (Papaya and Neem) have been reported to have adsorption qualities that, for the most part, agreed with the Langmuir adsorption isotherm model.References
Abro, I.A., Abro, M.I., Assad, M.E., Rahimi-Gorji, M., Hoang, N.M. (2020) Investigation and evaluation of neem leaves extract as a green inhibitor for corrosion behavior of mild steel: An experimental study.Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science, 235(4): 1-10
https://doi.org/10.1177/0954406220937723
Agarry, S.E., Oghenejoboh, K.M., Aworanti, O.A., Arinkoola, A.O. (2019) Biocorrosion inhibition of mild steel in crude oil-water environment using extracts of Musa paradisiaca peels, Moringa oleifera leaves, and Carica papaya peels as biocidal-green inhibitors: Kinetics and adsorption studies.Chemical Engineering Communications, 206(1): 98-124
https://doi.org/10.1080/00986445.2018.1476855
Akalezi, C.O., Enenebaku, C.K., Oguzie, E.E. (2003) Inhibition of acid corrosion of mild steel by biomass extract from the petersianthus macrocarpus plant.Journal of materials and environmental science, 4: 217-226, https://www.jmaterenvironsci.com/Document/vol4/vol4_N2/27-JMES-268-2012-Akalezi.pdf
Anyakwo, C.N., Ndukwe, A.I. (2017) Mathematical Model for Corrosion Inhibition of Mild Steel in Hydrochloric Acid by Crushed Leaves of Tridax procumbens (Asteraceae).International Journal of Science and Engineering Investigations, 6: 81-89, http://www.ijsei.com/papers/ijsei-66517-13.pdf
Anyakwo, C.N., Ndukwe, A.I. (2017) Prognostic Model for Corrosion Inhibition of Mild Steel in Hydrochloric Acid by Crushed Leaves of Voacanga Africana.International Journal of Computational and Theoretical Chemistry, 2: 31-42
Ayoola, A.A., Fayomi, O.S.I., Agboola, O., Durodola, B.M., Adegbite, A.O., Etoroma, A.A. (2021) Thermodynamic and Adsorption Influence on the Corrosion Inhibitive Performance of Pawpaw Seed on A36 Mild Steel in 1 M H2SO4 Medium.Journal of Bio-and Tribo-Corrosion, 7: 128
https://doi.org/10.1007/s40735-021-00555-y
Ayoola, A.A., Fayomi, O.S.I., Akande, I.G., Mgbahurike, F.C. (2021) Evaluation of the corrosion inhibitive behaviour of pawpaw fluid on a315 mild steel and A304 stainless steel In H2SO4 medium.Rasayan journal of chemistry, 14: 2506-2515
https://doi.org/10.31788/RJC.2021.1446352
Azadirachta, A.I. (2023) India Biodiversity Portal. https://indiabiodiversity.org/species/show/31068?us erGroupWebaddress=, 02.02.2023
Baitule, P., Manivannan, R. (2010) Corrosion inhibitory effect of Neem leaf extracts on mild steel in alkaline solution containing chloride ions.Journal of Indian Chemical Society, 97: 1061-1065
Benedict, E.C., Chime, T.O., Osoka, E. (2019) Optimization and effect of leaves extracts on corrosion of mild steal in acidic medium.International Journal of Bioscience, Biochemistry and Bioinformatics, 10(2): 117-126, http://www.ijbbb.org/show-84-933-1.html
https://doi.org/10.17706/ijbbb.2020.10.2.117-126
da Rocha, J.C., da Cunha, P.G.J.A., D'elia, E. (2010) Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extracts.Corrosion Science, 52(7): 2341-2348
https://doi.org/10.1016/j.corsci.2010.03.033
Dada, A.O., Olalekan, A.P., Olatunya, A.M., Dada, O. (2012) Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich Isotherms Studies of Equilibrium Sorption of Zn 2+ Unto Phosphoric Acid Modified Rice Husk.Journal of Applied Chemistry, 3: 38-45
https://doi.org/10.9790/5736-0313845
Fadare, O.O., Okoronkwo, A.E., Olasehinde, E.F. (2016) Assessment of anti-corrosion potentials of extract of Ficus asperifolia-Miq (Moraceae) on mild steel in acidic medium.African Journal of Pure and Applied Chemistry, 10(1): 8-22
https://doi.org/10.5897/AJPAC2015.0651
Faustin, M., Maciuk, A., Salvin, P., Roos, C., Lebrini, M. (2015) Corrosion inhibition of C38 steel by alkaloids extract of Geissospermum laeve in 1M hydrochloric acid: Electrochemical and phytochemical studies.Corrosion Science, 92: 287-300
https://doi.org/10.1016/j.corsci.2014.12.005
Gunavathy, N., Murugavel, S.C. (2012) Corrosion inhibition studies of mild steel in an acid medium using musa acuminata fruit peel extract.E-Journal of Chemistry, 9(1): 487-495
https://doi.org/10.1155/2012/952402
Heuzé, V., Tran, G., Archimède, H., Bastianelli, D., Lebas, F. (2015) Neem (Azadirachta indica). Feedipedia, a programme by INRAE, CIRAD, AFZ and FAO. https://www.feedipedia.org/node/182
Heuzé, V., Tran, G. (2015) Papaya (Carica papaya) fruits, leaves and by-products. Feedipedia, a programme by INRAE, CIRAD, AFZ and FAO. https://www.feedipedia.org/node/522
Hossain, N., Chowdhury, M.A., Kchaou, M. (2020) An overview of green corrosion inhibitors for sustainable and environment-friendly industrial development.Journal of Adhesion Science and Technology, 1: 1-18
Hukwueze, G.N., Aneke, N.A.G. (2019) Comparative analysis of corrosion inhibition of mild steel using pawpaw and neem leaves extracts in sulphuric acid medium.International journal of novel research in physics chemistry & mathemt, 6: 7-13
Ituen, E., Akaranta, O., James, A. (2017) Evaluation of performance of corrosion inhibitors using adsorption isotherm models: An overview.Chemical Science International Journal, 18(1): 1-34
https://doi.org/10.9734/CSJI/2017/28976
Jafari, H., Akbarzade, K., Danaee, I. (2019) Corrosion inhibition of carbon steel immersed in a 1 M HCl solution using benzothiazole derivatives.Arabian Journal of Chemistry, 12(7): 1387-1394
https://doi.org/10.1016/j.arabjc.2014.11.018
Khaled, K.F. (2012) A predictive model for corrosion inhibition of mild steel by thiophene and its derivatives using artificial neural network.International Journal of Electrochemical Science, 7: 1045-1059, http://www.electrochemsci.org/papers/ vol7/7021045.pdf
https://doi.org/10.1016/S1452-3981(23)13393-1
Kumar, H., Yadav, V., Kumari, A. (2022) Adsorption, corrosion inhibition mechanism, and computational studies of Azadirachta indica extract for protecting mild steel: Sustainable and green approach.Journal of Physics and Chemistry of Solids, 165: 110690-110690
https://doi.org/10.1016/j.jpcs.2022.110690
Laamari, R., Benzakour, J., Berrekhis, F., Abouelfida, A., Derja, A., Villemin, D. (2011) Corrosion inhibition of carbon steel in hydrochloric acid 0.5M by hexa methylene diamine tetramethyl-phosphonic acid.Arabian Journal of Chemistry, 4(3): 271-277
https://doi.org/10.1016/j.arabjc.2010.06.046
Montemor, M.F. (2016) Fostering green inhibitors for corrosion prevention. in: Hughes Mol A., Zheludkevich J., Buchheit M. [ed.] Active protective coatings: Springer series in materials science, Dordrecht: Springer, 233
https://doi.org/10.1007/978-94-017-7540-3_6
Mourya, P., Banerjee, S., Singh, M.M. (2014) Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor.Corrosion Science, 85: 352-363
https://doi.org/10.1016/j.corsci.2014.04.036
Nahlé, A., Abu-Abdoun, I., Abdel-Rahman, I., Al-Khayat, M. (2010) UAE Neem extract as a corrosion inhibitor for carbon steel in HCl solution.International Journal of Corrosion, 10: 1-9
https://doi.org/10.1155/2010/460154
Ndukwe, A.I. (2022) Green inhibitors for corrosion of metals in acidic media: A review.Academic Journal of Manufacturing Engineering, 20(2), 36-50, https://ajme.ro/PDF_AJME_2022_2/L5.pdf
Ndukwe, A.I., Anyakwo, C.N. (2017) Predictive model for corrosion inhibition of mild steel in HCl by crushed leaves of clerodendrum splendens.The international research journal of engineering and technology, 4: 679-688, https://irjet.net/archives/V4/i2/IRJET-V4I2129.pdf
Ndukwe, A.I., Anyakwo, C.N. (2017) Modelling of corrosion inhibition of mild steel in sulphuric acid by thoroughly crushed leaves of Voacanga Africana (Apocynaceae).American Journal of Engineering Research, 6: 344-356, http://www.ajer.org/papers/v6(01)/ZX060344356.pdf
Ndukwe, A.I., Anyakwo, C.N. (2017) Predictive Corrosion Inhibition Model for Mild Steel in Sulphuric Acid (H2SO4) by Leaf-Pastes of Sida Acuta Plant.Journal of Civil, Construction and Environmental Engineering, 2: 123-133
Ndukwe, A.I., Anyakwo, C.N. (2017) Corrosion Inhibition Model for Mild Steel in Sulphuric Acid by Crushed Leaves of Clerodendrum Splendens (Verbenaceae).International Journal of Scientific Engineering and Applied Science, 3: 39-49
Ndukwe, A.I., Anyakwo, C.N. (2019) Hindering the corrosion on mild steel in hydrochloric acid medium by the leaf-paste of Landolphia dulcis plant.International Journal of Scientific and Cultural Innovations and Sustainable Learning, 10: 10-35
Ndukwe, A.I. (2017) Corrosion inhibition of mild steel in acidic media by some plant-leaf pastes. Owerri: Federal University of Technology, Unpublished PhD Dissertation
Ndukwe, A.I., Anyakwo, C.N. (2017) Modelling of Corrosion Inhibition of Mild Steel in Hydrochloric Acid by Crushed Leaves of Sida Acuta (Malvaceae).The International Journal of Engineering and Science, 06(01): 22-33; http://www.theijes.com/papers/vol6-issue1 /Version-3/D0601032233.pdf
https://doi.org/10.9790/1813-0601032233
Nugroho, G., Pradityana, A., Husodo, N., Mursid, M., Winarto, G.D., Putrandi, F.T. (2018) Mechanism of papaya leaf as organic inhibitor in corrosion process. in: AIP Conference Proceedings, p.154
https://doi.org/10.1063/1.5046290
Nwigwe, S.U., Umunakwe, R., Mbam, S.O., Yibowei, M., Okon, K., Kalu-Uka, G. (2019) The Inhibition of Carica Papaya Leaves Extract on the Corrosion of Cold Worked and Annealed Mild Steel in HCl and NaOH Solutions Using a Weight Loss Technique.Engineering and Applied Science Research, 46: 114-119, https://ph01.tci-thaijo.org/index.php/easr/article/view/151118
Ogundana, I., Olalemi, A., Arotupin, D. (2022) Effect of aqueous extracts of leaves, stem, and seed of Azadirachta indica on corrosion inhibition of mild steels in acidic medium.Advanced Engineering Forum, 45: 15-30
https://doi.org/10.4028/p-l54c0w
Okewale, A., Omoruwuo, F. (2018) Neem leaf extract as a corrosion inhibitor on mild steel in acidic solution.International Journal of Engineering Research in Africa, 35: 208-220
https://doi.org/10.4028/www.scientific.net/JERA.35.208
Oki, M., Anawe, P.A., Fasakin, J. (2015) Performance of Mild Steel in Nitric Acid/Carica Papaya Leaf Extracts Corrosion System.Asian Journal of Applied Sciences, 3(1): 110-116, http://eprints.lmu.edu.ng/2613/1/1836-8319-1-PB.pdf
Okpala, A.N., Ogbonnaya, E.A., Waidi, Y.B. (2022) Effect of Azadirachta Indica (Neem) Leaf Extract on the Corrosion of Medium Carbon Steel in Sulphuric Acid.Research & Development, 3(2): 99-105
Omotioma, M., Onukwuli, O.D. (2016) Modeling the Corrosion Inhibition of Mild Steel in HCl Medium with the Inhibitor of Pawpaw Leaves Extract.Portugaliae Electrochimica Acta, 34(4): 287-294, http://www.peacta.org/articles_upload/PEA_34_4_2016_287_294.pdf
https://doi.org/10.4152/pea.201604287
Orwa, C., Mutua, A., Kindt, R., Jamnadass, R., Simons, A. (2019) Agroforestry database: A tree reference and a selection guide. http://apps.worldagro-forestry.org/treedb2/AFTPDFS/Carica_papaya.PDF
P.T. (2020) Papaya. in: Britannica, https://www. britannica.com/plant/papaya, 02.02.2023
Parthipan, P., Narenkumar, J., Elumalai, P., Preethi, P.S., Nanthini, A.U.R., Agrawal, A., Rajasekar, A. (2017) Neem extract as a green inhibitor for microbiologically influenced corrosion of carbon steel API 5LX in a hypersaline environments.Journal of Molecular Liquids, 240: 121-127
https://doi.org/10.1016/j.molliq.2017.05.059
Petruzzello, M. (2023) Azadirachta indica, margosa. in: Britannica, https://www.britannica.com/plant/neemtree, 02.02.2023
Popoola, L.T. (2019) Organic green corrosion inhibitors (OGCIs): A critical review.Corrosion Reviews, 37(2): 71-102
https://doi.org/10.1515/corrrev-2018-0058
Rani, B., Basu, B.B.J. (2012) Green inhibitors for corrosion protection of metals and alloys: An overview.International Journal of Corrosion, 1: 1-15
https://doi.org/10.1155/2012/380217
Sharma, S.K., Peter, A., Obot, I.B. (2015) Potential of Azadirachta indica as a green corrosion inhibitor against mild steel, aluminum, and tin: A review.Journal of Analytical Science and Technology, 6(1): 1-16
https://doi.org/10.1186/s40543-015-0067-0
Umoren, S.A., Eduok, U.M., Solomon, M.M., Udoh, A.P. (2016) Corrosion inhibition by leaves and stem extracts of Sida acuta for mild steel in 1M H2SO4 solutions investigated by chemical and spectroscopic techniques.Arabian Journal of Chemistry, 9(1): S209-S224
https://doi.org/10.1016/j.arabjc.2011.03.008
Valdez-Salas, B., Vazquez-Delgado, R., Salvador-Carlos, J., Beltran-Partida, E., Salinas-Martinez, R., Cheng, N., Curiel-Alvarez, M. (2021) Azadirachta indica leaf extract as green corrosion inhibitor for reinforced concrete structures: Corrosion effectiveness against commercial corrosion inhibitors and concrete integrity.Materials, 14(12), 1-14
https://doi.org/10.3390/ma14123326
Valek, L., Martinez, S. (2007) Copper corrosion inhibition by Azadirachta indica leaves extract in 0.5 M sulphuric acid.Materials Letters, 61(1): 148-151
https://doi.org/10.1016/j.matlet.2006.04.024
Verma, C., Ebenso, E.E., Bahadur, I., Quraishi, M.A. (2018) An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media.Journal of Molecular Liquids, 266: 577-590
https://doi.org/10.1016/j.molliq.2018.06.110
Waidi, Y.B., Philip, O.Y. (2022) Investigating the Efficacy of Azadirachta Indica (Neem) Leaf on Mild Steel Corrosion in 1M Sulphuric Acid (H2SO4).American Journal of Science, Engineering and Technology, 7: 121-129
Wei, H., Heidarshenas, B., Zhou, L., Hussain, G., Li, Q., Ostrikov, K. (2020) Green inhibitors for steel corrosion in acidic environment: State of art.Materials Today Sustainability, 10: 100044-100044
https://doi.org/10.1016/j.mtsust.2020.100044
Zaher, A., Aslam, R., Lee, H., Khafouri, A., Boufellous, M., Alrashdi, A.A., El, A.Y., Lgaz, H., Ouhssine, M. (2022) A combined computational & electrochemical exploration of the Ammi visnaga L. extracts as a green corrosion inhibitor for carbon steel in HCl solution.Arabian Journal of Chemistry, 15(2), 1-18
Downloads
Published
Issue
Section
License
Copyright (c) 2023 CC BY 4.0 by Authors
This work is licensed under a Creative Commons Attribution 4.0 International License.
