Inhibition of corrosion of mild steel by an alcoholic extract of a seaweed Sargassum muticum

Authors

  • Suyambulingam Jone Kirubavathy PSGR Krishnammal College for Women, Department of Chemistry, Coimbatore, India Author
  • Hashem Abdulhameed Al Kuwait Institute for Scientific Research, Petroleum Research Centre, Kuwait Author
  • Rajendran Susai Santhammal St. Antony's College of Arts and Sciences for Women Thamaraipadi, Corrosion Research Centre, PG Department of Chemistry, Tamil Nadu, India + Pondicherry University, India Author
  • R.M. Joany Sathyabama University, Department of ECE, Jeppiaar Nagar, Chennai, Tamil Nadu, India Author
  • Časlav Lačnjevac University of Belgrade, Faculty of Agriculture, Serbia Author

DOI:

https://doi.org/10.5937/zasmat2104304J

Keywords:

corrosion inhibition, mild steel, sea weed, Sargassum muticum, electrochemical studies, Langmuir adsorption isotherm, acid medium

Abstract

An alcoholic extract of a sea weed Sargassum muticum has been used to control corrosion of mild steel in 0.5 N HCl. Weight loss method and Electrochemical studies have been used in this study. Weight loss study reveals that 500 ppm of the inhibitor offers 99.25 % inhibition efficiency. Polarization study reveals that the inhibitor functions as an anodic inhibitor at higher concentration. The AC impedance spectra confirm the formation of a protective film on the metal surface. Adsorption of inhibitor molecules on the metal surface follows Langmuir adsorption isotherm.

References

Ajayi, O., Everitt, N., Voisey, K.T. (2017) Corrosion inhibition of mild steel in 15wt.% HCl by durum wheat. in: EUROCORR, The Annual Congress of the European Federation of Corrosion, 20th International Corrosion Congress and Process Safety Congress

Ajeigbe, S.O., Basar, N., Hassan, M.A., Aziz, M. (2017) Optimization of corrosion inhibition of essential oils of Alpinia galanga on mild steel using Response Surface Methodology.ARPN Journal of Engineering and Applied Sciences, 12(9), 2763-2771

Cenoui, M., Himer, I., Touir, R., Ebn, T.M., Dermaj, A., Hajjaji, N., El, K.H. (2010) Synergistic influence of molybdate ions on the inhibition of corrosion and scale of ordinary steel in cooling water system by new organic compound.Zaštita materijala, vol. 51, br. 1, str. 3-10

El-Taib, H.F., Deyab, M.A., Osman, M.M., Elkholy, A.E. (2018) Performance of Centaurea cyanus aqueous extract towards corrosion mitigation of carbon steel in saline formation water.Desalination, 425, 111-122

https://doi.org/10.1016/j.desal.2017.10.019

Fouda, A.S., Elewady, G.Y., El-Askalany, A., Shalabi, K. (2010) Inhibition of aluminum corrosion in hydrochloric acid media by three schiff base compounds.Zaštita materijala, vol. 51, br. 4, str. 205-219

Noreen, A., Sherine, B.H., Rajendran, S. (2010) Investigation of the inhibiting effect of nano film by sodium meta silicate: Zn2+ system on the corrosion of carbon steel in neutral chloride solution.Zaštita materijala, vol. 51, br. 1, str. 11-18

Parthipan, P., Narenkumar, J., Elumalai, P., Preethi, P.S., Usha, R.N.A., Agrawal, A., Rajasekar, A. (2017) Neem extract as a green inhibitor for microbiologically influenced corrosion of carbon steel API 5LX in a hypersaline environments.Journal of Molecular Liquids, 240, 121-127

https://doi.org/10.1016/j.molliq.2017.05.059

Pustaj, G., Kapor, F., Jakovljević, S. (2017) Carbon dioxide corrosion of carbon steel and corrosion inhibition by natural olive leaf extract [Die Kohlendioxid-Korrosion von Kohlenstoffstahl und die Korrosionshemmung durch natürlichen Olivenblattextrakt].Materialwissenschaft und Werkstofftechnik, 48(2), 122-138

https://doi.org/10.1002/mawe.201600598

Rajendran, S., Muthumegala, T.S., Pandiarajan, M., Devi, N.P., Krishnaveni, A., Jeyasundari, J., Samy, N.B., Beevi, H.N. (2011) Corrosion resistance of SS 316L in simulated concrete pore solution in presence of trisodium citrate.Zaštita materijala, vol. 52, br. 2, str. 85-89

Rajendran, S., Sribharathy, V., Krishnaveni, A., Jeyasundari, J., Sathiyabama, J., Muthumegala, T.S., Manivannan, M. (2011) Inhibition effect of self assembled films formed by adipic acid molecules on carbon steel surface.Zaštita materijala, vol. 52, br. 3, str. 163-172

Santos, R.S., Cordeiro, M.R., D'elia, R.F.B. (2017) A study of the gorse aqueous extract as a green corrosion inhibitor for mild steel in HCl aqueous solution.Green Chemistry Letters and Reviews, 10(4), 444-454

https://doi.org/10.1080/17518253.2017.1398354

Shehata, N.A., Saleh, M.F., Ghany, A., El, H.R.M. (2017) Novel corrosion inhibitors for acidizing oil wells.Materials and Corrosion, 68(3), 355-360

https://doi.org/10.1002/maco.201609146

Tezeghdenti, M., Etteyeb, N., Dhouibi, L., Kanoun, O., Al-Hamri, A. (2017) Natural products as a source of environmentally friendly corrosion inhibitors of mild steel in dilute sulphuric acid: Experimental and computational studies.Protection of Metals and Physical Chemistry of Surfaces, 53(4), 753-764

https://doi.org/10.1134/S2070205117040219

Umoren, S.A., Solomon, M.M., Obot, I.B., Suleiman, R.K. (2018) Comparative studies on the corrosion inhibition efficacy of ethanolic extracts of date palm leaves and seeds on carbon steel corrosion in 15% HCl solution.Journal of Adhesion Science and Technology, 32(17), 1934-1951

https://doi.org/10.1080/01694243.2018.1455797

Wu, S., Qiu, B., Fu, C., Wang, X. (2017) Inhibition effect of tangerine peel extract on J55 steel in CO2 -saturated 3.5wt.% NaCl solution.International Journal of Electrochemical Science, 12(12), 11195-11211

https://doi.org/10.20964/2017.12.02

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Published

15-12-2021

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