Zaštitno dejstvo magnetnog polja na koroziju aluminijumskih legura u rastvorima hlorovodonične kiseline
DOI:
https://doi.org/10.5937/zasmat2203271MKljučne reči:
Magnetno polje, legure aluminijuma, gravimetrijska tehnika, brzina korozije, efikasnost zaštite, poprečna magnetootpornostApstrakt
Gravimetrijskom tehnikom ispitan je uticaj primenjenih magnetnih polja na koroziju legura aluminijuma AA3003 i AA8011 u rastvorima hlorovodonične kiseline na sobnoj temperaturi. Magnetno polje je generisano od lokalno napravljenog elektromagneta sa promenljivim izlazima. Naneti su pod pravim uglom na površine uzoraka legure aluminijuma kada su potpuno uronjeni u ispitne rastvore. Pra ene su brzine korozije legura aluminijuma AA3003 i AA8011 u 0,5M rastvorima HCl kiselina pri različitim primenjenim magnetnim poljima. Rezultati pokazuju da se brzine korozije ispitivanih uzoraka legure aluminijuma smanjuju sa povećanjem primenjenog magnetnog polja. Ovo implicira da prisustvo magnetnog polja inhibira koroziju uzoraka legure aluminijuma AA3003 i AA8011. Sa primenjenim magnetnim poljima u opsegu od 254,3 - 1040,6 mG [0,0254 - 0,1041 mT , zaštitna efikasnost magnetnog polja primećena za AA3003 u 0,5M rastvorima HCl kiseline kre e se od 1 ,3 - 4,1 dok je za identičan rastvor aluminijuma AA80 allo1 test , efikasnost zaštite se kre e od 11,5 - 78,0%. Mehanizam zaštite se delom pripisuje fenomenu poprečne magnetootpornosti, a delom uticaju magnetnih polja na obrazac transporta mase konstitutivnih jona u elektrohemijskom sistemu.Reference
Al-Mayouf, A.M. (1996) Amino acids as corrosion inhibitors for aluminium in acid chloride solutions.Corros Prev. Ctrl, 6(1): 68-74
Ameer, M.A., Khamis, E., Al-Sanni, G. (2000) Adsorption studies of the effect of thiosemicarbazides on the corrosion of steel in phosphoric acid.Adsorpti. Sci. Tech, 18(3), 177 -194
https://doi.org/10.1260/0263617001493378
Animalu, A.O.E. (1977) Intermediate quantum theory of crystalline solids. New Jersey: Prentice-Hall Inc, 251-254
Anosike, G.C. (2012) Investigation of the effect of some local plant extracts and magnetic field on the corrosion of aluminium alloy AA3003 in hydrochloric acid solutions. Owerri, Nigeria: Federal University of Technology-Department of Physics, Bachelor of Science, B.Sc. Project Report, June, Unpublished
Callister, W.D. (2003) Materials science and engineering: An introduction. New York: John Wiley & Sons Inc, 6 th Edition, p. 579
Coosta, I., Oliveira, M.C.L., de Melo, H.G., Faria, R.N. (2004) The effect of magnetic field on the corrosion behaviour of Nd-Fe-B permanent magnets.J. Magn. & Magn. Mater, 278: 348-358
https://doi.org/10.1016/j.jmmm.2003.12.1320
Cruz, J., Martı'nez, R., Genesca, J., Garcı'a-Ochoa, E. (2004) Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media.Journal of Electroanalytical Chemistry, 566(1): 111-121
https://doi.org/10.1016/j.jelechem.2003.11.018
Duru, M.O. (2017) The effect of Alcohornea cordifolia leaf extract and magnetic field on the corrosion of Ti6Al4V exposed to simulated body fluids. Owerri, Nigeria: Federal University of Technology, M.Sc. Thesis, June, Unpublished
Ebenso, E.E., Udofot, J.J., Ibok, U.J., Ekpe, U.J. (1998) Studies on the inhibition of mild steel corrosion by some plant extracts in acidic medium.Discovery and Innovation, 10(1-2), str. 52-59
Flinn, R.A., Trojan, P.K. (1975) Engineering materials and their applications. Boston: Houghton-Mifflin Company, p. 42
Hu, J., Dong, C., Li, X., Xiao, K. (2010) Effects of applied magnetic field on corrosion of beryllium copper in NaCl solution.J. Mater. Sci. Technol, 26(4): 355-361
https://doi.org/10.1016/S1005-0302(10)60058-8
John, S., Joseph, B., Balakrishnan, K.V., Aravindakshan, K.K., Joseph, A. (2010) Electrochemical and quantum chemical study of 4-[(E)-[(2,4dihydroxyl phenyl) methylidine] amino]-6-methyl-3sulphanylidine-2,3,4,5-tetra hydro-1,2,4-triazin-5one [DMSTT].Mater. Chem. Phys, 123, 218 -224
https://doi.org/10.1016/j.matchemphys.2010.03.085
Kittel, C. (1963) Quantum theory of solids. New York: John Wiley & Sons Inc, 237-248
Lu, Z., Huang, D., Yang, W., Congleton, J. (2003) Effects of an applied magnetic field on the dissolution and passivation of iron in sulphuric acid.Corros. Sci, 45: 2233-2249
https://doi.org/10.1016/S0010-938X(03)00045-3
Maayta, A.K., Al-Rawashdeh, N.A.F. (2010) The inhibiting effects of alkyl benzene sulphonate and magnetic field on aluminium corrosion in acidic solution.Jordan J. Chem, 5(2): 175-189
https://doi.org/10.1155/2010/156194
Maayta, A.K., Fares, M.M., Shawabkeh, A.F. (2010) Influence of linear alkyl benzene sulphonate on corrosion of iron in the presence of magnetic field: Kinetic and thermodynamic parameters.Inter. J. Corros, 10, ID 156194
https://doi.org/10.1155/2010/156194
Martinez, S., Stern, I. (2001) Inhibitory mechanism of low-carbon steel corrosion by mimosa tannin in sulphuric acid solutions.Journal of Applied Electrochemistry, 31(9), 973-978
https://doi.org/10.1023/A:1017989510605
Mejeha, I.M., Uroh, A.A., Okeoma, K.B., Alozie, G.A. (2010) The inhibitive effect of Solanum melongena L leaf extract on the corrosion of aluminium in tetraoxosulphate VI acid.Afri. J. Pure Appl Chem, 4(8): 156-165
Mejeha, I.M., Nwandu, M.C., Okeoma, K.B., Nnanna, L.A., Chidiebere, M.A., Eze, F.C., Oguzie, E.E. (2012) Experimental and theoretical assessment of the inhibiting action of Aspilia africana extract on corrosion of aluminium alloy AA3003 in hydrochloric acid.J. Mater. Sci, 47(6): 2559-2572
https://doi.org/10.1007/s10853-011-6079-2
Metikoš, H.M., Babić, R., Grubač, Z. (2002) The study of aluminium corrosion in acidic solution with nontoxic inhibitors.Journal of Applied Electrochemistry, 32(1): 35-41
https://doi.org/10.1023/A:1014265407060
Nnanna, L.A., Onwuagba, B.N., Mejeha, I.M., Okeoma, K.B. (2010) Inhibition effects of some plant extracts on acid corrosion of aluminium alloy.Afri. J. Pure Appl. Chem, 4(1): 11-16
Nnanna, L.A., Anozie, I.U., Akoma, C.S., Mejeha, I.M., Okeoma, K.B., Mejeh, K.I. (2011) Corrosion control of aluminium alloy in alkaline solution using some leave extracts.Am. J. Mater. Sci, 1(2): 76-80
https://doi.org/10.5923/j.materials.20110102.12
Oguzie, E. (2008) Evaluation of the inhibitive effect of some plant extracts on the acid corrosion of mild steel.Corrosion Science, 50(11): 2993-2998
https://doi.org/10.1016/j.corsci.2008.08.004
Oguzie, E.E., Li, Y., Wang, F.H. (2007) Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion.Journal of Colloid and Interface Science, 310(1): 90
https://doi.org/10.1016/j.jcis.2007.01.038
Okeoma, K.B., Mejeha, I.M., Akajiaku, S.C., Eze, F.C., Orji, C.E. (2016) Investigative studies of on the inhibitive effects of Newbouldia laevis extracts and magnetic fields on copper corrosion in aqueous acidic media.Inter. J. Engineer. & Sci, 6(2): 5-14
Okeoma, K.B., Owate, I.O., Oguzie, E.E., Mejeha, I.M. (2012) Impacts of heat treatment on the electrochemical properties of AA3003 exposed to 0.1 M hydrochloric acid media.Am. J. Mater. Sci, 2(1): 51-58
https://doi.org/10.5923/j.materials.20120201.10
Okeoma, K.B., Owate, I.O., Oguzie, E.E., Mejeha, I.M. (2012) Effects of heat treatment on the electrochemical corrosion behaviour of aluminium alloy AA8011 in 0.1M H2SO4 aqueous acid media, Inter.J. Mater. Chem, 2(4): 178-184
Onuchukwu, A.I. (2008) Electrochemical Technology. Ibadan: Spectrum Books Ltd, p. 195 -226
Pillai, S.O. (2010) Solid state physics. New Delhi: New Age International Publishers, 276-276
Popova, A., Sokolova, E., Raicheva, S., Christov, M. (2003) AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives.Corrosion Science, 45(1): 33-58
https://doi.org/10.1016/S0010-938X(02)00072-0
Samir, L., Nasher, H., Buraq, L.A., Shalash, T. (2010) Study of the effects of magnetic field on the corrosion of steel in sodium chloride solution (NaCl).Misan J. Academic Studies, 19(17): 30-37
Slamova, M., Ocenasek, V., Cieslar, M., Chalupa, B., Merle, P. (2000) Differences in structure evolution of twin roll cast AA8006 and AA8011durring annealing.Mater. Sci. Forum, 331-337, 829 -834
https://doi.org/10.4028/www.scientific.net/MSF.331-337.829
Stokes, V.L. (1997) Manufacturing materials. Columbus OH: Charles E Merrill Publishing Company, 274-274
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