Characterization of vacuum plasma spray VPS - W coating deposited on stainless steel substrates

Authors

  • Darko Veljić University of Belgrade, Faculty of Technology and Metallurgy, Innovation Center, Serbia Author
  • Časlav Lačnjevac University of Belgrade, Faculty of Agriculture, Serbia Author
  • Marko Rakin University of Belgrade, Faculty of Technology and Metallurgy, Serbia Author

DOI:

https://doi.org/10.5937/zasmat2102106M

Keywords:

tungsten, vacuum plasma spray (VPS), microstructure, interface, microhardness, bond strength

Abstract

In this paper, studied was the melting of W powder particles in plasma, their behavior at oxidation as well as the mechanism of hardening on the surface of the substrate. Tungsten coating layers were deposited with vacuum plasma spray technology (VPS) on the test specimens of steel Č.4171 (X15Cr13 EN10027). VPS technology has advantages over the APS technology due to decreased oxidation of melted powder particles, by producing a coating with a controlled proportion of micro pores and greater uniformity of the deposited layers. Evaluation of mechanical characteristics of the layers was done by examining the microhardness using the HV0.3 method and tensile bond strength by tensile testing. The microstructures of the deposited layers were analyzed by means of optical microscopy (OM) and scanning electron microscopy (SEM). The results obtained showed that the tungsten coating consisted of well melted particles that interconnected and were overlapping, which shows a typical lamellar microstructure. Present in the microstructure are micro pores in very small proportion at the inter-lamellar boundaries. Tests have shown that layers of W coating deposited by plasma spray in inert gas shielding at low pressure have good mechanical properties and microstructure, which in the fully enables its use in exploitation.

References

(2002) Turbojet engine: Standard practices manual PN 582005. East Hartford, USA: Pratt & Whitney

Boire-Lavigne, S., Moreau, C., Saint-Jacques, R.G. (1993) Taguchi analysis of the influence of plasma spray parameters on the microstructure of tungsten coatings. in: International Symposium on Developments and Applications of Ceramics and New Metal Alloys, Quebec City, 473-485

Bolt, H., Barabash, V., Krauss, W., Linke, J., Neu, R., Suzuki, S., Yoshida, N., Asdex, U.T. (2004) Materials for the plasma-facing components of fusion reactors.Journal of Nuclear Materials, 329-333: 66-73

https://doi.org/10.1016/j.jnucmat.2004.04.005

Cai, W., Liu, H., Sickinger, A., Muehlberger, E., Bailey, D., Lavernia, E.J. (1994) Low-pressure plasma deposition of tungsten.Journal of Thermal Spray Technology, 3(2): 135-141

https://doi.org/10.1007/BF02648270

Cavasin, A., Brzezinski, T., Grenier, S., Smagorinski, M., Tsantrizos, P. (1998) W and B4 C coatings for nuclear fusion reactors. in: International Thermal Spray Conference, Nice, France: ASM International

https://doi.org/10.31399/asm.cp.itsc1998p0957

Chong, F.L., Chen, J.L., Li, J.G., Hu, D.Y., Zheng, X.B. (2008) Heat load behaviors of plasma sprayed tungsten coatings on copper alloys with different compliant layers.Journal of Nuclear Materials, 375(2): 213-217

https://doi.org/10.1016/j.jnucmat.2007.11.008

Fortuna, E., Rubel, M.J., Psoda, M., Andrzejczuk, M., Kurzydowski, K.J., Miskiewicz, M., Philipps, V., Pospieszczyk, A., Sergienko, G., Spychalski, M., Zielinski, W. (2007) Plasma-induced damage of tungsten coatings on graphite limiters.Physica Scripta, T128: 162-165

https://doi.org/10.1088/0031-8949/2007/T128/031

Hu, D., Zheng, X., Niu, Y., Ji, H., Chong, F., Chen, J. (2008) Effect of oxidation behavior on the mechanical and thermal properties of plasma sprayed tungsten coatings.Journal of Thermal Spray Technology, 17(3): 377-384

https://doi.org/10.1007/s11666-008-9190-4

Jiang, X.L., Boulos, M.I. (2001) Particle melting, flattening, and stacking behaviors in the induction plasma deposition of tungsten.Transactions of Nonferrous Metals Society of Chinam, 11(5): 811-816

Kang, H.K. (2004) Thermal properties of plasma-sprayed tungsten deposits.Journal of Nuclear Materials, 335(1): 1-4

https://doi.org/10.1016/j.jnucmat.2004.06.001

Malléner, W., Hohenauer, W., Stöver, D. (1996) Tungsten coatings for nuclear fusion devices. in: 9th National Thermal Spray Conference. Cincinnatti, proceedings, Cincinnatti, p.1-6

https://doi.org/10.31399/asm.cp.itsc1996p0001

Mrdak, M.R., Vencl, A., Nedeljković, B.D., Stanković, M. (2013) Influence of plasma spraying parameters on properties of thermal barrier coatings.Materials Science and Technology, 29(5): 559-567

https://doi.org/10.1179/1743284712Y.0000000193

Mrdak, M., Lačnjevac, Č., Rakin, M. (2018) Mechanical and structural features of Nb coating layers deposited on steel substrates in a vacuum chamber.Zaštita materijala, vol. 59, br. 2, str. 167-172

https://doi.org/10.5937/ZasMat1802167M

Mrdak, M., Lačnjevac, Č., Rakin, M., Bajić, N. (2018) Characterization of tantalum coatings deposited using vacuum plasma spray process.Zaštita materijala, vol. 59, br. 4, str. 489-494

https://doi.org/10.5937/zasmat1804489M

Mrdak, M., Lačnjevac, Č., Rakin, M., Bajić, N., Veljić, D. (2019) Karakterizacija plazma sprej bioinertne prevlake Al2O328tež.%MgO.Zaštita materijala, vol. 60, br. 1, str. 44-49

https://doi.org/10.5937/zasmat1901044M

Niu, Y., Zheng, X., Ji, H., Qi, L., Ding, C., Chen, J., Luo, G. (2010) Microstructure and thermal property of tungsten coatings prepared by vacuum plasma spraying technology.Fusion Engineering and Design, 85(7-9): 1521-1526

https://doi.org/10.1016/j.fusengdes.2010.04.032

Pintsuk, G., Brünings, S.E., Döring, J.-.E., Linke, J., Smid, I., Xue, L. (2003) Development of W/Cu-functionally graded materials.Fusion Engineering and Design, 66-68: 237-240

https://doi.org/10.1016/S0920-3796(03)00220-5

Raman, R., Thomas, J.C., Hwang, D.Q., Conway, G.D., Martin, F., Hirose, A., Gierszewski, P., Décoste, R. (1993) Design of the compact toroid fueler for center fueling tokamak de varennes.Fusion Technology, 24(3): 239-250

https://doi.org/10.13182/FST93-A30198

Salhi, Z., Klein, D., Gougeon, P., Coddet, C. (2005) Development of coating by thermal plasma spraying under very low-pressure condition <1mbar.Vacuum, 77(2): 145-150

https://doi.org/10.1016/j.vacuum.2004.08.013

Stolarski, T.A., Tobe, S. (2001) The effect of spraying distance on wear resistance of molybdenum coatings.Wear, 249(12): 1096-1102

https://doi.org/10.1016/S0043-1648(01)00842-0

Tokunaga, K., Yoshida, N., Noda, N., Kubota, Y., Inagaki, S., Sakamoto, R., Sogabe, T., Plöchl, L. (1999) Behavior of plasma-sprayed tungsten coatings on CFC and graphite under high heat load.Journal of Nuclear Materials, 266-269: 1224-1229

https://doi.org/10.1016/S0022-3115(98)00689-8

Tran, A.T.T., Hyland, M.M., Shinoda, K., Sampath, S.S. (2011) Influence of substrate surface conditions on the deposition and spreading of molten droplets.Thin Solid Films, 519(8): 2445-2456

https://doi.org/10.1016/j.tsf.2010.11.047

Warren, A., Nylund, A., Olefjord, I. (1996) Oxidation of tungsten and tungsten carbide in dry and humid atmospheres.International Journal of Refractory Metals and Hard Materials, 14(5-6): 345-353

https://doi.org/10.1016/S0263-4368(96)00027-3

Downloads

Published

15-06-2021

Issue

Section

Articles