Corrosion inhibition efficiency of the Myrrh Gum on API 5CTP110 tubing in hydrochloric acid

Authors

  • Abde lmadjid Atassi Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria Author
  • Mounir Djellab Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria; Laboratoire de Génie des procédés chimiques et de l’environnement, University of Biskra, Biskra, Algeria Author
  • Hamza Bentrah Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria; Laboratoire de Génie des procédés chimiques et de l’environnement, University of Biskra, Biskra, Algeria Author https://orcid.org/0000-0002-9199-317X
  • Abdelouahad Chala Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria Author
  • Mohamed Cherif Ben Ameur Politecnico di Milano, Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Milano, Italy Author
  • Slimane Kherief Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria Author
  • Ridha Azzouz Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria; Centre de recherche scientifique et technique des régions arides de Biskra, University of Biskra, Biskra, Algeria Author
  • Amir Eddine Kabouia Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria Author
  • Bouzid Bouamra Laboratory of Physics of Thin Films and Applications, University of Biskra, Biskra, Algeria Author

DOI:

https://doi.org/10.62638/ZasMat1393

Abstract

The corrosion inhibition properties of Myrrh Gum (MG) on API 5CT P110 tubing in  0.5 M HCl solution were investigated using electrochemical techniques, including electrochemical impedance spectroscopy and potentiodynamic polarization. The study demonstrated that MG exhibits exceptional inhibitory performance, achieving an efficiency of 92% at an optimal concentration of 3 g/L. The analysis revealed that the adsorption of MG molecules onto the steel surface follows the Langmuir isotherm model, indicating a process dominated by physical adsorption. Additionally, MG acts as a mixed-type inhibitor, effectively mitigating both anodic and cathodic reactions. These findings highlight the potential of Myrrh Gum as a cost-effective and environmentally friendly corrosion inhibitor for industrial applications, particularly in acidic environments. The use of MG aligns with sustainable practices, providing a viable alternative to traditional synthetic inhibitors and contributing to the development of green corrosion prevention strategies.

Keywords:

Eco-friendly corrosion inhibitor, API 5CT P110 tubing, Myrrh Gum, Hydrochloric acid, EIS

References

K. Haruna, I. Obot, N. Ankah, A. Sorour, T. Saleh (2018) Gelatin: A green corrosion inhibitor for carbon steel in oil well acidizing environment, J. Mol. Liq., 264, 515-525. https://doi.org/10.1016/j.molliq.2018.05.058. DOI: https://doi.org/10.1016/j.molliq.2018.05.058

W. Zhang, H.-J. Li, M. Wang, L.-J. Wang, F. Shang, Y.-C. Wu (2018) Halogen-substituted acridines as highly effective corrosion inhibitors for mild steel in acid medium, J. Phys. Chem. C, 122, 25349-25364. https://doi.org/10.1021/acs.jpcc.8b07015. DOI: https://doi.org/10.1021/acs.jpcc.8b07015

A.H. Alamri (2020) Localized corrosion and mitigation approach of steel materials used in oil and gas pipelines – An overview, Eng. Fail. Anal., 116, 104735. https://doi.org/10.1016/j.engfailanal.2020.104735. DOI: https://doi.org/10.1016/j.engfailanal.2020.104735

M.A.M. El-Haddad, A. Bahgat Radwan, M.H. Sliem, W.M.I. Hassan, A.M. Abdullah (2019) Highly efficient eco-friendly corrosion inhibitor for mild steel in 5 M HCl at elevated temperatures: experimental & molecular dynamics study, Sci. Rep., 9, 3695. https://doi.org/10.1038/s41598-019-40149-w. DOI: https://doi.org/10.1038/s41598-019-40149-w

M. Goyal, S. Kumar, I. Bahadur, C. Verma, E.E. Ebenso (2018) Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: A review, J. Mol. Liq., 256, 565-573. https://doi.org/10.1016/j.molliq.2018.02.045. DOI: https://doi.org/10.1016/j.molliq.2018.02.045

A. Singh M.A. Quraishi (2015) Acidizing corrosion inhibitors: a review, J. Mater. Environ. Sci, 6, 224-235.

D. Dwivedi, K. Lepková, T. Becker (2017) Carbon steel corrosion: a review of key surface properties and characterization methods, RSC Adv., 7, 4580-4610. DOI: https://doi.org/10.1039/C6RA25094G DOI: https://doi.org/10.1039/C6RA25094G

A. Frignani, C. Monticelli, F. Zucchi, G. Trabanelli (2014) Acetylenic alcohols as inhibitors of iron acid corrosion. Improvement of the inhibition efficiency of a class of substances based on their action mechanism, Int. J. Corros. Scale Inhib, 3, 105. https://doi.org/10.17675/2305-6894-2014-3-2-105-119. DOI: https://doi.org/10.17675/2305-6894-2014-3-2-105-119

M. Salman, K. Ansari, V. Srivastava, D.S. Chauhan, J. Haque, M. Quraishi (2021) Chromeno naphthyridines based heterocyclic compounds as novel acidizing corrosion inhibitors: Experimental, surface and computational study, J. Mol. Liq., 322, 114825. https://doi.org/10.1016/j.molliq.2020.114825. DOI: https://doi.org/10.1016/j.molliq.2020.114825

M. Galai, M.E. Touhami, M. Oubaaqa, K. Dahmani, M. Ouakki, M. Khattabi, Z. Benzekri, R. lachhab, S. Kaya, N. Bulut, S. Briche, S. Boukhris (2023) Electrochemical, Characterization, and Quantum Chemical Studies of Two Newly Synthesized Aromatic Aldehydes-Based Xanthene Diones as Corrosion Inhibitors for Mild Steel in 1 M Hydrochloric Acid, J. Bio- Tribo-Corros., 9, 63. https://doi.org/10.1007/s40735-023-00778-1. DOI: https://doi.org/10.1007/s40735-023-00778-1

J. Wang, L. An, J. Wang, J. Gu, J. Sun, X. Wang (2023) Frontiers and advances in N-heterocycle compounds as corrosion inhibitors in acid medium: Recent advances, Adv. Colloid Interface Sci., 103031. https://doi.org/10.1016/j.cis.2023.103031. DOI: https://doi.org/10.1016/j.cis.2023.103031

M. Yadav, S. Kumar, P. Yadav (2013) Corrosion Inhibition of Tubing Steel during Acidization of Oil and Gas Wells, J. Pet. Eng., 2013. https://doi.org/10.1155/2013/354630. DOI: https://doi.org/10.1155/2013/354630

D. Singh A. Dey (1993) Synergistic effects of inorganic and organic cations on inhibitive performance of propargyl alcohol on steel dissolution in boiling hydrochloric acid solution, Corrosion, 49, 594-600. https://doi.org/10.5006/1.3316090. DOI: https://doi.org/10.5006/1.3316090

F.G. Liu, M. Du, J. Zhang, M. Qiu (2009) Electrochemical behavior of Q235 steel in saltwater saturated with carbon dioxide based on new imidazoline derivative inhibitor, Corros. Sci., 51, 102-109. https://doi.org/10.1016/j.corsci.2008.09.036. DOI: https://doi.org/10.1016/j.corsci.2008.09.036

X. Li, S. Deng, H. Fu, G. Mu (2010) Synergistic inhibition effect of rare earth cerium(IV) ion and sodium oleate on the corrosion of cold rolled steel in phosphoric acid solution, Corros. Sci., 52, 1167-1178. https://doi.org/10.1016/j.corsci.2009.12.017. DOI: https://doi.org/10.1016/j.corsci.2009.12.017

X. Li, S. Deng, H. Fu, G. Mu (2009) Synergistic inhibition effect of rare earth cerium(IV) ion and 3,4-dihydroxybenzaldehye on the corrosion of cold rolled steel in H2SO4 solution, Corros. Sci., 51, 2639-2651. https://doi.org/10.1016/j.corsci.2009.06.047. DOI: https://doi.org/10.1016/j.corsci.2009.06.047

S.Y. Al-Nami A.E.-A.S. Fouda (2020) Corrosion Inhibition Effect and Adsorption Activities of methanolic myrrh extract for Cu in 2 M HNO3, Int. J. Electrochem. Sci., 15, 1187-1205. https://doi.org/10.20964/2020.02.23. DOI: https://doi.org/10.20964/2020.02.23

B. Tan, B. Xiang, S. Zhang, Y. Qiang, L. Xu, S. Chen, J. He (2021) Papaya leaves extract as a novel eco-friendly corrosion inhibitor for Cu in H2SO4 medium, J. Colloid Interface Sci., 582, 918-931. https://doi.org/10.1016/j.jcis.2020.08.093. DOI: https://doi.org/10.1016/j.jcis.2020.08.093

N. Hossain, M. Asaduzzaman Chowdhury, M. Kchaou (2021) An overview of green corrosion inhibitors for sustainable and environment friendly industrial development, J. Adhes. Sci. Technol., 35, 673-690. https://doi.org/10.1080/01694243.2020.1816793. DOI: https://doi.org/10.1080/01694243.2020.1816793

M. Rinaudo (2014) Biomateriales basados en un polisacárido natural: el alginato, TIP Revista Especializada en Ciencias Químico-Biológicas, 17, 92-96.

H. Hu, J. Li, W. Jiang, Y. Jiang, Y. Wan, Y. Wang, F. Xin, W. Zhang (2024) Strategies for the biological synthesis of D-glucuronic acid and its derivatives, World J. Microbiol. Biotechnol., 40, 94. https://doi.org/10.1007/s11274-024-03900-8. DOI: https://doi.org/10.1007/s11274-024-03900-8

A. Wadouachi J. Kovensky (2011) Synthesis of Glycosides of Glucuronic, Galacturonic and Mannuronic Acids: An Overview, Molecules, 16, 3933-3968. https://doi.org/10.3390/molecules16053933. DOI: https://doi.org/10.3390/molecules16053933

A. Richel, F. Nicks, P. Laurent, B. Wathelet, J.-P. Wathelet, M. Paquot (2012) Efficient microwave-promoted synthesis of glucuronic and galacturonic acid derivatives using sulfuric acid impregnated on silica, Green Chemistry Letters and Reviews, 5, 179-186. https://doi.org/10.1080/17518253.2011.607852. DOI: https://doi.org/10.1080/17518253.2011.607852

C.-S. Wu (2009) Renewable resource-based composites of recycled natural fibers and maleated polylactide bioplastic: Characterization and biodegradability, Polym. Degrad. Stab., 94, 1076-1084. https://doi.org/10.1016/j.polymdegradstab.2009.04.002. DOI: https://doi.org/10.1016/j.polymdegradstab.2009.04.002

A. Singh, K.R. Ansari, D.S. Chauhan, M.A. Quraishi, H. Lgaz, I.-M. Chung (2020) Comprehensive investigation of steel corrosion inhibition at macro/micro level by ecofriendly green corrosion inhibitor in 15% HCl medium, J. Colloid Interface Sci., 560, 225-236. https://doi.org/10.1016/j.jcis.2019.10.040. DOI: https://doi.org/10.1016/j.jcis.2019.10.040

M. Djellab, H. Bentrah, A. Chala, H. Taoui, S. Kherief, B. Bouamra (2020) Synergistic effect of iodide ions and bark resin of Schinus molle for the corrosion inhibition of API5L X70 pipeline steel in H2SO4, Mater. Corros., 71, 1276-1288. https://doi.org/10.1002/maco.202011533. DOI: https://doi.org/10.1002/maco.202011533

D. Wang, Y. Li, B. Chen, L. Zhang (2020) Novel surfactants as green corrosion inhibitors for mild steel in 15% HCl: Experimental and theoretical studies, Chem. Eng. J., 402, 126219. https://doi.org/10.1016/j.cej.2020.126219. DOI: https://doi.org/10.1016/j.cej.2020.126219

S.A. Umoren (2016) Polypropylene glycol: A novel corrosion inhibitor for ×60 pipeline steel in 15% HCl solution, J. Mol. Liq., 219, 946-958. https://doi.org/10.1016/j.molliq.2016.03.077. DOI: https://doi.org/10.1016/j.molliq.2016.03.077

M. Djellab, H. Bentrah, A. Chala, H. Taoui (2019) Synergistic effect of halide ions and gum arabic for the corrosion inhibition of API5L X70 pipeline steel in H2SO4, Mater. Corros., 70, 149-160. https://doi.org/10.1002/maco.201810203. DOI: https://doi.org/10.1002/maco.201810203

R. Solmaz, G. Kardaş, M. Çulha, B. Yazıcı, M. Erbil (2008) Investigation of adsorption and inhibitive effect of 2-mercaptothiazoline on corrosion of mild steel in hydrochloric acid media, Electrochim. Acta, 53, 5941-5952. https://doi.org/10.1016/j.electacta.2008.03.055. DOI: https://doi.org/10.1016/j.electacta.2008.03.055

I.B. Obot, A. Meroufel, I.B. Onyeachu, A. Alenazi, A.A. Sorour (2019) Corrosion inhibitors for acid cleaning of desalination heat exchangers: Progress, challenges and future perspectives, J. Mol. Liq., 296, 111760. https://doi.org/10.1016/j.molliq.2019.111760. DOI: https://doi.org/10.1016/j.molliq.2019.111760

H. Taoui, H. Bentrah, A. Chala, M. Djellab (2019) Bark resin of Schinus molle as an eco-friendly inhibitor for API 5L X70 pipeline steel in HCl medium, Mater. Corros., 70, 511-520. https://doi.org/10.1002/maco.201810477. DOI: https://doi.org/10.1002/maco.201810477

O. Sotelo-Mazon, S. Valdez, J. Porcayo-Calderon, M. Casales-Diaz, J. Henao, G. Salinas-Solano, J.L. Valenzuela-Lagarda, L. Martinez-Gomez (2019) Corrosion protection of 1018 carbon steel using an avocado oil-based inhibitor, Green Chemistry Letters and Reviews, 12, 255-270. https://doi.org/10.1080/17518253.2019.1629698. DOI: https://doi.org/10.1080/17518253.2019.1629698

M.M. Solomon, S.A. Umoren, A.U. Israel, I.G. Etim (2016) Synergistic inhibition of aluminium corrosion in H2SO4 solution by polypropylene glycol in the presence of iodide ions, Pigment Resin Technol., 45, 280-293. https://doi.org/10.1108/PRT-01-2015-0010. DOI: https://doi.org/10.1108/PRT-01-2015-0010

H. Bentrah, Y. Rahali, A. Chala (2014) Gum Arabic as an eco-friendly inhibitor for API 5L X42 pipeline steel in HCl medium, Corros. Sci., 82, 426-431. https://doi.org/10.1016/j.corsci.2013.12.018. DOI: https://doi.org/10.1016/j.corsci.2013.12.018

E. Ebenso, N. Eddy, A. Odiongenyi (2009) Corrosion Inhibition and Adsorption Properties of Methocarbamol on Mild Steel in Acidic Medium, Port. Electrochim. Acta, 27, 13-22. https://doi.org/10.4152/pea.200901013. DOI: https://doi.org/10.4152/pea.200901013

S. Kherief, M. Djellab, H. Bentrah, A. Chala, B. Bouamra, H. Taoui (2023) Corrosion Inhibition Efficiency of Ghars Date Extract on API 5L X70 Pipeline Steel in Hydrochloric Acid, Protection of Metals and Physical Chemistry of Surfaces, 59, 1306-1314. https://doi.org/10.1134/S2070205123701162. DOI: https://doi.org/10.1134/S2070205123701162

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Published

15-03-2026

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Scientific paper