Application of fly ash for flouride adsorption

Authors

  • Jelena Vuković University of East Sarajevo, Faculty of Technology, Zvornik, Republic of Srpska, B&H Author
  • Milomirka Obrenović University of East Sarajevo, Faculty of Technology, Zvornik, Republic of Srpska, B&H Author
  • Slavko Smiljanić University of East Sarajevo, Faculty of Technology, Zvornik, Republic of Srpska, B&H Author

DOI:

https://doi.org/10.5937/zasmat2204395V

Keywords:

fly ash, adsorption, fluorides, wastewater

Abstract

The suitable characteristics of fly ash from thermal power plants make it a proper adsorbent for removing various pollutants from water and aqueous solutions. Valorization and utilization of fly ash can reduce the use of conventional adsorbents. The paper presents an overview of the possibility of using raw and modified fly ash to remove fluorides from water and aqueous solutions, as well as the influence of different process parameters (sorbent dose, contact time, pH value, temperature, etc.) on the value of adsorption capacity and adsorption efficiency of used sorbent. Fly ash can be used as an effective sorbent for the removal of fluoride, both in raw and modified form, with given optimal process parameters. Raw fly ash shows better adsorption properties when performing the experiment in a column, with a higher dose of sorbent and longer contact time, in an acidic environment (pH = 2-3), compared to batch experiments. Various authors have modified fly ash by treatment with certain chemical agents (HCl, Ca (OH)2…) or by synthesis of zeolite based on fly ash. Modification of fly ash improves its adsorption properties, so in slightly acidic conditions (pH = 6), for a relatively short contact time (10-30 min), in batch conditions, significant adsorption efficiency (~ 90%) can be achieved.

References

Fly Ash Market by Type (Type F, Type C), Application (Portland Cement & Concrete, Bricks & Blocks, Road Construction, Agriculture), and Region (Asia Pacific, Europe, North America, Middle East & Africa, South America) - Global Forecast to 2023. https://www.marketsandmarkets.com/Market-Reports/fly-ash-market-76345803.html, 31.5.2022

Fly ash market - growth, trends, COVID-19 impact, and forecasts (2022 -2027). https://www. mordorintelligence.com/industry-reports/fly-ashmarket, 31.5.2022

Fly Ash Market Size, Share & Industry Analysis, By Type (Class F and Class C), by Application (Cement & concretes, Fills & embankments, Waste Stabilization, Mining, Oil field Service and Road Stabilization and Others), and Regional Forecast, 2020-202. https://www.fortunebusinessinsights. com/industry-reports/fly-ash-market-101087, 31.5. 2022

(2016) Production and Utilisation of CCPs in 2016 in Europe. http://www.ecoba.com/evjm, media /ccps/ECO_stat_2016_EU15_tab.pdf, 26.02.2022

Ahmaruzzaman, M. (2010) A review on the utilization of fly ash.Progress in energy and combustion science, 36(3), 327-363

https://doi.org/10.1016/j.pecs.2009.11.003

Akafu, T., Chimdi, A., Gomoro, K. (2019) Removal of Fluoride from Drinking Water by Sorption Using Diatomite Modified with Aluminium Hydroxide.Journal of Analytical Methods in Chemistry, Volume 2019, Article ID 4831926, 1-11

https://doi.org/10.1155/2019/4831926

Ali, S., Thakur, S.K., Sarkar, A., Shekhar, S. (2016) Worldwide contamination of water by fluoride.Environmental chemistry letters, 14(3), 291-315

https://doi.org/10.1007/s10311-016-0563-5

Argiz, C., Menéndez, E., Moragues, A., Sanjuán, M.A. (2015) Fly ash characteristics of Spanish coal-fired power plants.Afinidad, 72(572)

Artiola, J.F., Walworth, J.L., Musil, S.A., Crimmins, M.A. (2019) Soil and land pollution, book In Environmental and pollution science. Amsterdam: Academic Press, pp 219-235

https://doi.org/10.1016/B978-0-12-814719-1.00014-8

ASTM, American Society for Testing Materials (2005) ASTM standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete (C618-05). in: Annual book of ASTM standards, concrete and aggregates, West Conshohocken: ASTM International, vol. 04.02

Babel, S., Kurniawan, T.A. (2003) Low-cost adsorbents for heavy metals uptake from contaminated water: a review.Journal of hazardous materials, 97(1-3), 219-243

https://doi.org/10.1016/S0304-3894(02)00263-7

Bazrafshan, E., Balarak, D., Panahi, A.H., Kamani, H., Mahvi, A.H. (2016) Fluoride removal from aqueous solutions by cupricoxide nanoparticles.Fluoride, 49(3), 233

Bhatnagar, A., Kumare, E., Sillanpää, M. (2011) Fluoride removal from water by adsorption-a review.Chemical engineering journal, 171(3), 811-840

https://doi.org/10.1016/j.cej.2011.05.028

Bhavyalekshmi, R., Madhu, G. (2016) Performance evaluation of fly ash as low cost adsorbent for fluoride removal.Rem, 40, 60

Çelik, Ö., Dam, E.I., Pişkin, S. (2008) Characterization of fly ash and it effects on the compressive strength properties of Portland cement.Indian Journal of Engineering and Material Sciences, 15(5)

Chakraborty, G.M., Das, S.K., Mandal, S.N. (2016) in: International Conference on Pure and Applied Chemistry, Switzerland: Springer, p. 69-87

Chandraker, N., Jyoti, G., Thakur, R.S., Chaudhari, P.K. (2020)IOP Conference Series: Earth and Environmental Science, 597, IOP Publishing, Bandung, Indonesia, p 012009

https://doi.org/10.1088/1755-1315/597/1/012009

Chaturvedi, A.K., Yadava, K.P., Pathak, K.C., Singh, V.N. (1990) Defluoridation of water by adsorption on fly ash.Water, Air, and Soil Pollution, 49(1), 51-61

https://doi.org/10.1007/BF00279509

Chen, J., Yang, R., Zhang, Z., Wu, D. (2022) Removal of fluoride from water using aluminum hydroxideloaded zeolite synthesized from coal fly ash.Journal of Hazardous Materials, 421, 126817

https://doi.org/10.1016/j.jhazmat.2021.126817

Chidambaram, S., Ramanathan, A.L., Vasudevan, S. (2003) Fluoride removal studies in water using natural materials.Water Sa, 29(3), 339-344

https://doi.org/10.4314/wsa.v29i3.4936

Dwivedi, A., Jain, M.K. (2014) Fly ash-waste management and overview: A Review.Recent Research in Science and Technology, 6(1)

Fawell, J., Bailey, K., Chilton, J., Dahi, E., Magara, Y. (2006) Fluoride in drinking-water. London: IWA publishing, p. 5-8

Ge, J.C., Yoon, S.K., Choi, N.J. (2018) Application of fly ash as an adsorbent for removal of air and water pollutants.Applied Sciences, 8(7), 1116

https://doi.org/10.3390/app8071116

Geethamani, C.K., Ramesh, S.T., Gandhimathi, R., Nidheesh, P.V. (2014) Alkali-treated fly ash for the removal of fluoride from aqueous solutions.Desalination and Water Treatment, 52(19-21), 3466-3476

https://doi.org/10.1080/19443994.2013.800825

Jha, S.K., Mishra, V.K., Sharma, D.K., Damodaran, T. (2011) Fluoride in the environment and its metabolism in humans.Reviews of Environmental Contamination and Toxicology, Volume 211, 121-142

https://doi.org/10.1007/978-1-4419-8011-3_4

Joshi, R.C., Lohtia, R.P. (1997) Fly ash in concrete: production, properties and uses. Alberta, Canada: CRC Press, Vol. 2

Kandel, S., Vogel, J., Penn, C., Brown, G. (2017) Phosphorus retention by fly ash amended filter media in aged bioretention cells.Water, 9(10), 746

https://doi.org/10.3390/w9100746

Kofa, G.P., Gomdje, V.H., Telegang, C., Koungou, S.N. (2017) Removal of fluoride from water by adsorption onto fired clay pots: kinetics and equilibrium studies.Journal of applied chemistry, 1-7

https://doi.org/10.1155/2017/6254683

Kumar, P.S., Suganya, S., Srinivas, S., Priyadharshini, S., Karthika, M., Karishma, S.R., Swetha, V., Naushad, M., Lichtfouse, E. (2019) Treatment of fluoride-contaminated water: A review.Environmental Chemistry Letters, 17(4), 1707-1726

https://doi.org/10.1007/s10311-019-00906-9

Lennon, M.A., Whelton, H., O'mullane, D., Ekstrand, J. (2004) Fluoride, Rolling revision of the WHO guidelines for drinking-water quality. World Health

Lü, H., Wang, B., Ban, Q. (2010) Defluoridation of drinking water by zeolite NaP1 synthesized from coal fly ash.Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 32(16), 1509-1516

https://doi.org/10.1080/15567030902780352

Mann, S., Mandal, A. (2014) Removal of fluoride from drinking water using sawdust.International Journal of Engineering Research and Applications, 4(7), 116-123

Medical Research Council Working Group (2002) Water fluoridation and health, Report. London: MRC, https://bfsweb.org/water-fluoridation-andhealth-medical-research-council-2002/, 20.2.2022

Nemade, P.D., Vasudeva, R.A., Alappat, B.J. (2002) Removal of fluorides from water using low cost adsorbents.Water Science and Technology: Water Supply, 2(1), 311-317

https://doi.org/10.2166/ws.2002.0037

Panda, L., Kar, B.B. (2018) Preparation of fly ash based zeolite for fluoride removal.Asian Journal of Water, Environment and Pollution, 15(4), 105-113

https://doi.org/10.3233/AJW-180063

Petersen, P.E., Lennon, M.A. (2004) Effective use of fluorides for the prevention of dental caries in the 21st century: the WHO approach.Community dentistry and oral epidemiology, 32(5), 319-321

https://doi.org/10.1111/j.1600-0528.2004.00175.x

PHO, Public Health Ontario (2018) Ontario Agency for Health Protection and Promotion, Evidence review for adverse health effects of drinking optimally fluoridated water: evidence since the 2010 Health Canada fluoride document. Toronto, ON: Queen's Printer for Ontario

Physicians for Social Responsibility (PSR) (2018) Coal ash: hazardous to your health.Physicians for Social Responsibility, https://www. psr. org/wp-content/uploads/2018/05/coal-ashhazardous-to-human-health.pdf , 21.2.2022

Piekos, R., Paslawska, S. (1999) Fluoride uptake characteristics of fly ash.Fluoride, 32, 14-19

Ranasinghe, R.A.J.C., Hansima, M.A.C.K., Nanayakkara, K.G.N. (2022) Adsorptive removal of fluoride from water by chemically modified coal fly ash: Synthesis, characterization, kinetics, and mechanisms.Groundwater for Sustainable Development, 16, 100699

https://doi.org/10.1016/j.gsd.2021.100699

Saravanakumar, P., Gopalakrishnan, P., Sivakamidevi, M., Archana, E.S. (2019) Domestic wastewater treatment using flyash as adsorbent.International Journal of Engineering and Advanced Technology, 8(5), 1465 -1468

Sarwar, A.F.M., Hoque, A.K.M., Fazlul, H.A.K.M., Khan, M.H., Nessa, J. (2018) Fluoride in drinking water and its health consequences. https://www.researchgate.net/publication/32468386 4_Fluoride_in_drinking_water_and_its_health_cons equences, 21.2.2022

Shah, S.F.A., Aftab, A., Soomro, N., Nawaz, M.S., Vafai, K. (2015) Waste water treatment-bed of coal fly ash for dyes and pigments industry.Pakistan Journal of Analytical & Environmental Chemistry, 16(2), 9

Singh, J., Singh, P., Singh, A. (2016) Fluoride ions vs removal technologies: A study.Arabian Journal of Chemistry, 9, 815-824

https://doi.org/10.1016/j.arabjc.2014.06.005

Skousen, J., Yang, J.E., Lee, J.S., Ziemkiewicz, P. (2013) Review of fly ash as a soil amendment.Geosystem Engineering, 16(3), 249-256

https://doi.org/10.1080/12269328.2013.832403

Souakri, S., Reess, T., de Ferron, A.S., Lemont, F., Marchand, M. (2016) Flue Gas Treatment by ESP: Realization and Optimization of an Emissive Electrode.International Journal of Plasma Environmental Science and Technology, 10(2), 173-180

Sujana, M.G., Thakur, R.S., Rao, S.B. (1998) Removal of fluoride from aqueous solution by using alum sludge.Journal of Colloid and Interface Science, 206(1), 94-101

https://doi.org/10.1006/jcis.1998.5611

Sutton, M., Kiersey, R., Farragher, L., Long, J. (2015) Health effects of water fluoridation, Report. Health Research Board, https://www.hrb.ie/fileadmin/ publications_files/Health_Effects_of_Water_Fluorid ation.pdf, 20.2.2022

Šešlija, M., Rosić, A., Radović, N., Vasić, M., Đogo, M., Jotić, M. (2016) Laboratorijska ispitivanja elektrofilterskog pepela.Tehnički vjesnik, 23(6), 1839-1848

Tanikella, P., Olek, J. (2017) Updating physical and chemical characteristics of fly ash for use in concrete. in: Joint Transportation Research Program Publication, West Lafayette: Purdue University, No. FHWA/IN/JTRP-2017/11

https://doi.org/10.5703/1288284315213

United States Environmental Protection Agency (2011) Questions and Answers on Fluoride. https://www.epa.gov/sites/production/files/2015-10/documents/2011_fluoride_questionsanswers.pdf, 20.2.2022

Upadhyay, A., Kamal, M. (2007) Characterization and utilization of fly ash. Rourkela, Orissa: National institute of technology - Department of mining engineering, Doctoral dissertation

Visa, M., Nacu, M., Carcel, R.A. (2011) in: World of Coal Ash (WOCA) Conference -May, Denver, USA, p. 9-12

Wang, Y., Reardon, E.J. (2001) Activation and regeneration of a soil sorbent for defluoridation of drinking water.Applied Geochemistry, 16(5), 531-539

https://doi.org/10.1016/S0883-2927(00)00050-0

Wardhono, A. (2018)IOP Conference Series: Materials Science and Engineering, 288, IOP Publishing, Bandung, Indonesia, p. 012019

https://doi.org/10.1088/1757-899X/288/1/012019

World Health Organization (WHO) (2008) 'Guidelines for drinking-water quality '': Incorporating the first and second addenda. Geneva, Switzerland: World Health Organization (WHO), vol. 1, 3 rd edition

Xu, X., Li, Q., Cui, H., Pang, J., Sun, L., An, H., Zhai, J. (2011) Adsorption of fluoride from aqueous solution on magnesia-loaded fly ash cenospheres.Desalination, 272(1-3), 233-239

https://doi.org/10.1016/j.desal.2011.01.028

Ye, C., Yan, B., Ji, X., Liao, B., Gong, R., Pei, X., Liu, G. (2019) Adsorption of fluoride from aqueous solution by fly ash cenospheres modified with paper mill lime mud: Experimental and modeling.Ecotoxicology and Environmental Safety, 180, 366-373

https://doi.org/10.1016/j.ecoenv.2019.04.086

Downloads

Published

15-12-2022

Issue

Section

Articles