Clay and clay minerals: A brief review from fundamentals to applications

Authors

DOI:

https://doi.org/10.62638/ZasMat1138

Abstract

Clay and clay minerals are naturally occurring materials and available abundantly on the earth. They are inexpensive, and have a range of structures and properties with mechanical and heat stability. They are layered magnesium or aluminium silicates composed of tetrahedrally coordinated silicate sheets and octahedrally coordinated magnesium or aluminium hydroxide sheets. Because of natural abundance and environment friendly nature, clay and clay minerals have been used in different industrial sectors. In this review article, classification of clay minerals, structures, properties and their applications in different sectors have been discussed. Some of the important sectors, where clay and clay minerals are being used extensively are Agriculture and farming, Fertilizers and soil conditioners, Pesticides and Herbicides, Animal feeds, Food industry, Detergent industry, Cosmetic and pharmaceutical industry, Biomedical industry, Textile and paint industry, Oil and gas Exploration, Construction Industry, Environmental Protection, Carbon dioxide capture, Photocatalysis, etc. We tried to update the current knowledge with recent developments and progress in clay and clay minerals in this review.

Keywords:

clay, clay minerals, structure, property, applications, agriculture industry, pharmaceutical industry
Supporting Agencies
Sharda university

References

F. Bergaya, G. Lagaly (2013) General introduction: clays, clay minerals, and clay science, Dev. Clay Sci., 5, 1-19. https://doi.org/10.1016/B978-0-08-098258-8.00001-8 DOI: https://doi.org/10.1016/B978-0-08-098258-8.00001-8

M. Kotal, A.K. Bhowmick (2015) Polymer nanocomposites from modified clays: Recent advances and challenges, Prog. Polym. Sci., 51, 127-187. https://doi.org/10.1016/j.progpolymsci.2015.10.001 DOI: https://doi.org/10.1016/j.progpolymsci.2015.10.001

M.M. Orta, J. Martin, J. Santos, I. Aparicio, S. Medina-Carrasco, E. Alonso (2020) Biopolymer-clay nanocomposites as novel and ecofriendly adsorbents for environmental remediation, Appl. Clay Sci., 198, 105838. https://doi.org/10.1016/j.clay.2020.105838 DOI: https://doi.org/10.1016/j.clay.2020.105838

P.G. Balkanloo, A.P. Marjani, F. Zanbili, M. Mahmoudian (2022) Clay mineral/polymer composite: characteristics, synthesis, and application in Li-ion batteries: A review, Appl. Clay Sci., 228, 106632. https://doi.org/10.1016/j.clay.2022.106632 DOI: https://doi.org/10.1016/j.clay.2022.106632

K. Wal, P. Rutkowski, W. Stawinski (2021) Application of clay minerals and their derivatives in adsorption from gaseous phase, Appl. Clay Sci., 215, 106323. https://doi.org/10.1016/j.clay.2021.106323 DOI: https://doi.org/10.1016/j.clay.2021.106323

J.H. Yang, J.H. Lee, H.J. Ryu, A.A. Elzatahry, Z.A. Alothman, J.H. Choy (2016) Drug-clay nanohybrids as sustained delivery systems, Appl. Clay Sci., 130, 20-32. https://doi.org/10.1016/j.clay.2016.01.021 DOI: https://doi.org/10.1016/j.clay.2016.01.021

G.E. Christidis (2011) Industrial clays, EMU Notes Mineral., 9, 341-414. https://doi.org/10.1180/emu-notes.2010.emu9-9 DOI: https://doi.org/10.1180/emu-notes.2010.emu9-9

N. Kumari, C. Mohan (2021) Basics of clay minerals and their characteristic properties, https://doi.org/10.5772/intechopen.97672 DOI: https://doi.org/10.5772/intechopen.97672

F. Wypych, R.A. de Freitas (2022) Clay minerals: Classification, structure, and properties, Dev. Clay Sci., 10, 1-35. https://doi.org/10.1016/B978-0-323-91858-9.00004-5 DOI: https://doi.org/10.1016/B978-0-323-91858-9.00004-5

A. Hamza, I.A. Hussein, M. Mahmoud (2023) Introduction to reservoir fluids and rock properties, Dev. Pet. Sci., 78, 1-19. https://doi.org/10.1016/B978-0-323-99285-5.00003-X DOI: https://doi.org/10.1016/B978-0-323-99285-5.00003-X

C.G. Kim (2013) Adsorption/ion exchange of metal ions on clay mineral surfaces, Asian J. Chem., 25(10), 5884. https://doi.org/10.14233/ajchem.2013.OH118 DOI: https://doi.org/10.14233/ajchem.2013.OH118

F. Anouar, A. Elmchaouri, N. Taoufik, Y. Rakhila (2019) Investigation of the ion exchange effect on surface properties and porous structure of clay: Application of ascorbic acid adsorption, J. Environ. Chem. Eng., 7(5), 103404. https://doi.org/10.1016/j.jece.2019.103404 DOI: https://doi.org/10.1016/j.jece.2019.103404

S.C. Aboudi Mana, M.M. Hanafiah, A.J.K. Chowdhury (2017) Environmental characteristics of clay and clay-based minerals, Geol. Ecol. Landsc., 1(3), 155-161. https://doi.org/10.1080/24749508.2017.1361128 DOI: https://doi.org/10.1080/24749508.2017.1361128

L. Vaculikova, V. Valovicova, E. Plevova, B.D. Napruszewska, D. Duraczynska, R. Karcz, E.M. Serwicka (2021) Synthesis, characterization and catalytic activity of cryptomelane/montmorillonite composites, Appl. Clay Sci., 202, 105977. https://doi.org/10.1016/j.clay.2021.105977 DOI: https://doi.org/10.1016/j.clay.2021.105977

D.K. Dutta (2018) Clay mineral catalysts, Dev. Clay Sci., 9, 289-329. https://doi.org/10.1016/B978-0-08-102432-4.00009-3 DOI: https://doi.org/10.1016/B978-0-08-102432-4.00009-3

J.A. Cecilia, C.P. Jimenez-Gomez (2021) Catalytic applications of clay minerals and hydrotalcites, Catalysts, 11(1), 68. https://doi.org/10.3390/catal11010068 DOI: https://doi.org/10.3390/catal11010068

R.W. McCabe, J.M. Adams (2013) Clay minerals as catalysts, Dev. Clay Sci., 5, 491-538. https://doi.org/10.1016/B978-0-08-098259-5.00019-6 DOI: https://doi.org/10.1016/B978-0-08-098259-5.00019-6

K.M. Manjaiah, R. Mukhopadhyay, R. Paul, S.C. Datta, P. Kumararaja, B. Sarkar (2019) Modified clay and zeolite nanocomposite materials, Elsevier. https://doi.org/10.1016/B978-0-12-814617-0.00008-6 DOI: https://doi.org/10.1016/B978-0-12-814617-0.00008-6

G.J. Churchman (2018) Game changer in soil science: Functional role of clay minerals in soil, J. Plant Nutr. Soil Sci., 181(1), 99-103. https://doi.org/10.1002/jpln.201700605 DOI: https://doi.org/10.1002/jpln.201700605

D. Merino, B. Tomadini, M.F. Salcedo, A.Y. Mansilla, C.A. Casalongue, V.A. Alvarez (2020) Nanoclay as carriers of bioactive molecules applied to agriculture, In: Handbook of Nanomaterials and Nanocomposites for Energy and Environment Applications, Springer. https://doi.org/10.1007/978-3-030-11155-7_62-1 DOI: https://doi.org/10.1007/978-3-030-11155-7_62-1

G.K. Kome, R.K. Enang, F.O. Tabi, B.P.K. Yerima (2019) Influence of clay minerals on some soil fertility attributes: A review, Open J. Soil Sci., 9(9), 155-188. https://doi.org/10.4236/ojss.2019.99010 DOI: https://doi.org/10.4236/ojss.2019.99010

C. Song, Y. Guan, D. Wang, D. Zewudie, F. Li (2014) Palygorskite-coated fertilizers with a timely release of nutrients increase potato productivity in a rain-fed cropland, Field Crops Res., 166, 10-17 https://doi.org/10.1016/j.fcr.2014.06.015 DOI: https://doi.org/10.1016/j.fcr.2014.06.015

L. Tian, J. Liu, X. Guo, L. Li, X. Liu (2013) Effects of water saving materials on soil physical characters and maize yield in loess plateau, Adv. J. Food Sci. Technol., 5(2), 186-191. https://doi.org/10.19026/ajfst.5.3242 DOI: https://doi.org/10.19026/ajfst.5.3242

M. Pateiro-Moure, J.C. Nóvoa-Muñoz, M. Arias-Estévez, E. López-Periago, E. Martínez-Carballo, J. Simal-Gándara (2009) Quaternary herbicides retention by the amendment of acid soils with a bentonite-based waste from wineries, J. Hazard. Mater., 164(2-3), 769-775. https://doi.org/10.1016/j.jhazmat.2008.08.071 DOI: https://doi.org/10.1016/j.jhazmat.2008.08.071

I.M.S. Gajić, S.T. Stojiljković, I.M. Savić, D. Gajić (2014) Industrial applications of clays and clay minerals, In: Clays Clay Miner.: Geol. Orig., Mech. Prop. Ind. Appl., Nova.

H.H. Murray (2006) Structure and composition of clay minerals and their physical and chemical properties, In: Appl. Clay Mineral., 2, 7-31. https://doi.org/10.1016/S1572-4352(06)02002-2 DOI: https://doi.org/10.1016/S1572-4352(06)02002-2

J.C. Masini, G. Abate (2021) Guidelines to study the adsorption of pesticides onto clay minerals aiming at a straightforward evaluation of their removal performance, Minerals, 11(11), 1282. https://doi.org/10.3390/min11111282 DOI: https://doi.org/10.3390/min11111282

T. Undabeytia, U. Shuali, S. Nir, B. Rubin (2020) Applications of chemically modified clay minerals and clays to water purification and slow release formulations of herbicides, Minerals, 11(1), 9. https://doi.org/10.3390/min11010009 DOI: https://doi.org/10.3390/min11010009

S. Nir, Y. El-Nahhal, T. Undabeytia, G. Rytwo, T. Polubesova, Y. Mishael, O. Rabinovitz, B. Rubin (2006) Clays and pesticides, In: Handb. Clay Sci., 685-699. https://doi.org/10.1016/S1572-4352(05)01021-4 DOI: https://doi.org/10.1016/S1572-4352(05)01021-4

S. Nir, Y. El-Nahhal, T. Undabeytia, G. Rytwo, T. Polubesova, Y. Mishael, O. Rabinovitz, B. Rubin (2013) Clays, clay minerals, and pesticides, Dev. Clay Sci., 5, 645-662. https://doi.org/10.1016/B978-0-08-098259-5.00022-6 DOI: https://doi.org/10.1016/B978-0-08-098259-5.00022-6

D. Kovačević, J. Lemić, M. Damjanović, R. Petronijević, D. Janacković, T. Stanić (2011) Fenitrothion adsorption-desorption on organo-minerals, Appl. Clay Sci., 52(1-2), 109-114. https://doi.org/10.1016/j.clay.2011.02.006 DOI: https://doi.org/10.1016/j.clay.2011.02.006

A. Damato, F. Vinello, E. Novelli, S. Balzan, M. Gianesella, E. Giaretta, G. Gabai (2022) Comprehensive review on the interactions of clay minerals with animal physiology and production, Front. Vet. Sci., 9. https://doi.org/10.3389/fvets.2022.889612 DOI: https://doi.org/10.3389/fvets.2022.889612

M. Nadziakiewicz, S. Kehoe, P. Micek (2019) Physico-chemical properties of clay minerals and their use as a health promoting feed additive, Animals, 9(10), 714. https://doi.org/10.3390/ani9100714 DOI: https://doi.org/10.3390/ani9100714

R. Slamová, M. Tréková, H. Vondrusková, Z. Zralý, I. Pavlík (2011) Clay minerals in animal nutrition, Appl. Clay Sci., 51, 395-398. https://doi.org/10.1016/j.clay.2011.01.005 DOI: https://doi.org/10.1016/j.clay.2011.01.005

Z. Amanzougarene, M. Fondevila (2022) Rumen fermentation of feed mixtures supplemented with clay minerals in a semicontinuous in vitro system, Animals, 12(3), 345. https://doi.org/10.3390/ani12030345 DOI: https://doi.org/10.3390/ani12030345

M.D. Subramanium, I.H. Kim (2015) Clays as dietary supplements for swine: A review, J. Anim. Sci. Biotechnol., 6(38). https://doi.org/10.1186/s40104-015-0037-9 DOI: https://doi.org/10.1186/s40104-015-0037-9

N. Zhang, X. Han, Y. Zhao, Y. Li, J. Meng, H. Zhang, J. Liang (2022) Removal of aflatoxin B1 and zearalenone by clay mineral materials: In the animal industry and environment, Appl. Clay Sci., 228, 106614. https://doi.org/10.1016/j.clay.2022.106614 DOI: https://doi.org/10.1016/j.clay.2022.106614

A.A. Al-Arfaj, A.M. Murugan, C. Arunachalam, M.I. Al-Hazmi (2013) Cost-effective bentonite clayed pyramid technologies for household fruits and vegetables storage, J. Food Agric. Environ., 11(2), 175-180.

S. Diblan, M. Özkan (2013) Effects of various clarification agents on the anthocyanins of red wines, GIDA-J. Food, 38(1), 47-54.

M. Kaur, H.K. Sharma, S. Patil, A. Shitandi (2021) Optimization of ethanol concentration, glycerol concentration and temperature conditions of grape-mahua wine to maximize the quality and overall acceptability, J. Microbiol. Biotechnol. Food Sci., 2021, 2426-2430.

E. Lira, F.N. Salazar, J.J. Rodriguez-Bencomo, S. Vincenzi, A. Curioni, F. López (2014) Effect of using bentonite during fermentation on protein stabilisation and sensory properties of white wine, Int. J. Food Sci. Technol., 49(4), 1070-1078. https://doi.org/10.1111/ijfs.12402 DOI: https://doi.org/10.1111/ijfs.12402

M. Lambri, R. Dordoni, M. Giribaldi, M.R. Violetta, M.G. Giuffrida (2012) Heat-unstable protein removal by different bentonite labels in white wines, LWT-Food Sci. Technol., 46(2), 460-467. https://doi.org/10.1016/j.lwt.2011.11.022 DOI: https://doi.org/10.1016/j.lwt.2011.11.022

Z.X. Li, G.M. Wang, Q. Liang (2013) Preparation and properties of the novel adsorbent agent for juices clarification, Adv. Mater. Res., 791, 248-251. https://doi.org/10.4028/www.scientific.net/AMR.791-793.248 DOI: https://doi.org/10.4028/www.scientific.net/AMR.791-793.248

E.L. Foletto, D.S. Paz, A. Gündel (2013) Acid-activation assisted by microwave of a Brazilian bentonite and its activity in the bleaching of soybean oil, Appl. Clay Sci., 83, 63-67. https://doi.org/10.1016/j.clay.2013.08.017 DOI: https://doi.org/10.1016/j.clay.2013.08.017

O. Lacin, E. Sayan, E.G. Kirali (2013) Optimization of acid-activated bentonites on bleaching of cotton oil, J. Chem. Soc. Pak., 35(4), 1053-1059.

S. Jeempadiphat, D.N. Tungasmita (2014) Esterification of oleic acid and high acid content palm oil over an acid-activated bentonite catalyst, Appl. Clay Sci., 87, 272-277. https://doi.org/10.1016/j.clay.2013.11.025 DOI: https://doi.org/10.1016/j.clay.2013.11.025

F.J. Rodríguez, A. Torres, Á. Peñaloza, H. Sepúlveda, M.J. Galotto, A. Guarda, J. Bruna (2014) Development of an antimicrobial material based on a nanocomposite cellulose acetate film for active food packaging, Food Addit. Contam. Part A, 31(3), 342-353. https://doi.org/10.1080/19440049.2013.876105 DOI: https://doi.org/10.1080/19440049.2013.876105

S.L. Park, S.Y. Lee, H.J. Kim, S.I. Lim, Y.D. Nam, I.M. Kang (2015) Application of clay minerals in the food industry, Econ. Environ. Geol., 48(3), 255-260. https://doi.org/10.9719/EEG.2015.48.3.255 DOI: https://doi.org/10.9719/EEG.2015.48.3.255

A.K. Jha, A.K. Jha, A.K. Mishra, V. Kumari, B. Mishra (2011) Softening of hard water by bentonite mineral, Asian J. Water Environ. Pollut., 8(4), 93-96. https://doi.org/10.3233/AJW-2011-8_4_12 DOI: https://doi.org/10.3233/AJW-2011-8_4_12

F.L.G. Hsu, S.P. Zhu, Y.P. Zhu (2006) Aqueous detergent composition containing ethoxylated fatty acid di-ester, U.S. Patent 7,098,175.

M.A. Atieh (2011) Removal of zinc from water using modified and non-modified carbon nanofibers, In: 2nd Int. Conf. Environ. Sci. Technol., 6.

F.J. CarriónFité (2009) The effect of bentonite microparticles in the washing of cotton fabric, In: 9th World Textile Conf. AUTEX 2009, 1180-1186.

M. Ghadiri, W. Chrzanowski, R. Rohanizadeh (2015) Biomedical applications of cationic clay minerals, RSC Adv., 5(37), 29467-29481. https://doi.org/10.1039/C4RA16945J DOI: https://doi.org/10.1039/C4RA16945J

I.S. Khurana, S. Kaur, H. Kaur, R.K. Khurana (2015) Multifaceted role of clay minerals in pharmaceuticals, Future Sci. OA, 1(3), 45-53. https://doi.org/10.4155/fso.15.6 DOI: https://doi.org/10.4155/fso.15.6

M.I. Carretero, M. Pozo (2010) Clay and non-clay minerals in the pharmaceutical and cosmetic industries Part II.Active ingredients, Appl. Clay Sci., 47(3-4), 171-181. https://doi.org/10.1016/j.clay.2009.10.016 DOI: https://doi.org/10.1016/j.clay.2009.10.016

M.I. Carretero, M. Pozo (2009) Clay and non-clay minerals in the pharmaceutical industry: Part I. Excipients and medical applications, Appl. Clay Sci., 46(1), 73-80. https://doi.org/10.1016/j.clay.2009.07.017 DOI: https://doi.org/10.1016/j.clay.2009.07.017

N. Selvasudha, U.M. Dhanalekshmi, S. Krishnaraj, Y.H. Sunder, N.S.D. Devi, I. Sarathchandiran (2020) Multifunctional clay in pharmaceuticals, In: Clay Sci. Technol., IntechOpen. https://doi.org/10.5772/intechopen.92408 DOI: https://doi.org/10.5772/intechopen.92408

C. Nomicisio, M. Ruggeri, E. Bianchi, B. Vigani, C. Valentino, C. Aguzzi, C. Viseras, S. Rossi, G. Sandri (2023) Natural and synthetic clay minerals in the pharmaceutical and biomedical fields, Pharmaceutics, 15(5), 1368. https://doi.org/10.3390/pharmaceutics15051368 DOI: https://doi.org/10.3390/pharmaceutics15051368

C. Viseras, R. Sánchez-Espejo, R. Palumbo, N. Liccardi, F. García-Villén, A. Borrego-Sánchez, M. Massaro, S. Riela, A. López-Galindo (2021) Clays in cosmetics and personal-care products, Clays Clay Miner., 69(5), 561-575. https://doi.org/10.1007/s42860-021-00154-5 DOI: https://doi.org/10.1007/s42860-021-00154-5

J.D.D. Moraes, S.R.A. Bertolino, S.L. Cuffini, D.F. Ducart, P.E. Bretzke, G.R. Leonardi (2017) Clay minerals: Properties and applications to dermocosmetic products and perspectives of natural raw materials for therapeutic purposes-A review, Int. J. Pharm., 534(1-2), 213-219. https://doi.org/10.1016/j.ijpharm.2017.10.031 DOI: https://doi.org/10.1016/j.ijpharm.2017.10.031

M. Massaro, C.G. Colletti, G. Lazzara, S. Riela (2018) The use of some clay minerals as natural resources for drug carrier applications, J. Funct. Biomater., 9(4), 58-62. https://doi.org/10.3390/jfb9040058 DOI: https://doi.org/10.3390/jfb9040058

M.C. Da Rocha, T. Galdino, P. Trigueiro, L.M. Honorio, R. de Melo Barbosa, S.M. Carrasco, E.C. Silva-Filho, J.A. Osajima, C. Viseras (2022) Clays as vehicles for drug photostability, Pharmaceutics, 14(4), 796. https://doi.org/10.3390/pharmaceutics14040796 DOI: https://doi.org/10.3390/pharmaceutics14040796

T. Ito, T. Sugafuji, M. Maruyama, Y. Ohwa, T. Takahashi (2001) Skin penetration by indomethacin is enhanced by use of an indomethacin/smectite complex, J. Supramol. Chem., 1(4-6), 217-219. https://doi.org/10.1016/S1472-7862(02)00028-X DOI: https://doi.org/10.1016/S1472-7862(02)00028-X

J.K. Park, Y.B. Choy, J.M. Oh, J.Y. Kim, S.J. Hwang, J.H. Choy (2008) Controlled release of donepezil intercalated in smectite clays, Int. J. Pharm., 359(1-2), 198-204. https://doi.org/10.1016/j.ijpharm.2008.04.012 DOI: https://doi.org/10.1016/j.ijpharm.2008.04.012

J.W. McGinity, J.L. Lach (1977) Sustained-release applications of montmorillonite interaction with amphetamine sulfate, J. Pharm. Sci., 66(1), 63-66. https://doi.org/10.1002/jps.2600660115 DOI: https://doi.org/10.1002/jps.2600660115

D. Johnson, B. Gegel, J. Burgett, J. Gasko, C. Cromwell, M. Jaskowska, R. Steward, A. Taylor (2012) The effects of QuikClot Combat Gauze on hemorrhage control, Int. Sch. Res. Notices, 2012. https://doi.org/10.5402/2012/927678 DOI: https://doi.org/10.5402/2012/927678

S. Demaneche, L. Jocteur-Monrozier, H. Quiquampoix, P. Simonet (2001) Evaluation of biological and physical protection against nuclease degradation of clay-bound plasmid DNA, Appl. Environ. Microbiol., 67(1), 293-299. https://doi.org/10.1128/AEM.67.1.293-299.2001 DOI: https://doi.org/10.1128/AEM.67.1.293-299.2001

F.H. Lin, C.H. Chen, W.T. Cheng, T.F. Kuo (2006) Modified montmorillonite as vector for gene delivery, Biomaterials, 27(17), 3333-3338. https://doi.org/10.1016/j.biomaterials.2005.12.029 DOI: https://doi.org/10.1016/j.biomaterials.2005.12.029

D. Depan, A.P. Kumar, R.P. Singh (2009) Cell proliferation and controlled drug release studies of nanohybrids based on chitosan-g-lactic acid and montmorillonite, Acta Biomater., 5(1), 93-100. https://doi.org/10.1016/j.actbio.2008.08.007 DOI: https://doi.org/10.1016/j.actbio.2008.08.007

C. Mousty (2004) Sensors and biosensors based on clay-modified electrodes-new trends, Appl. Clay Sci., 27(3-4), 159-177. https://doi.org/10.1016/j.clay.2004.06.005 DOI: https://doi.org/10.1016/j.clay.2004.06.005

F. Charmantray, N. Touisni, L. Hecquet, C. Mousty (2013) Amperometric biosensor based on galactose oxidase immobilized in clay matrix, Electroanalysis, 25(3), 630-635. https://doi.org/10.1002/elan.201200274 DOI: https://doi.org/10.1002/elan.201200274

R. Nisticò (2022) A comprehensive study on the applications of clays into advanced technologies, with a particular attention on biomedicine and environmental remediation, Inorganics, 10(3), 40. https://doi.org/10.3390/inorganics10030040 DOI: https://doi.org/10.3390/inorganics10030040

M.P. Gashti, R. Rashidian, A. Almasian, A.B. Zohouri (2013) A novel method for colouration of cotton using clay nano-adsorbent treatment, Pigment Resin Technol., 42(3), 175-185. https://doi.org/10.1108/03699421311317343 DOI: https://doi.org/10.1108/03699421311317343

M. Parvinzadeh, I. Ebrahimi (2011) Atmospheric air-plasma treatment of polyester fiber to improve the performance of nanoemulsion silicone, Appl. Surf. Sci., 257(9), 4062-4068. https://doi.org/10.1016/j.apsusc.2010.11.175 DOI: https://doi.org/10.1016/j.apsusc.2010.11.175

M. ParvinzadehGashti, B. Katozian, M. Shaver, A. Kiumarsi (2014) Clay nanoadsorbent as an environmentally friendly substitute for mordants in the natural dyeing of carpet piles, Color. Technol., 130(1), 54-61. https://doi.org/10.1111/cote.12065 DOI: https://doi.org/10.1111/cote.12065

C.W.M. Yuen, C.W. Kan, H.L. Lee (2006) Improving wrinkle resistance of cotton fabric by montmorillonite, FibersPolym., 7(2), 139-145. https://doi.org/10.1007/BF02908258 DOI: https://doi.org/10.1007/BF02908258

S. Nehra, J.B. Dahiya, S. Kumar (2013) Effect of nanoclays on thermal and flame retardant properties of intumescent coated cotton fabric, Asian J. Res. Chem., 6(7), 676-682.

C.R.S. Oliveira, M.A. Batistella, L.A. Lourenco, S.M.A.G.U. de Souza, A.A. de Souza (2021) Cotton fabric finishing based on phosphate/clay mineral by direct-coating technique and its influence on the thermal stability of the fibers, Prog. Org. Coat., 150, 105949. https://doi.org/10.1016/j.porgcoat.2020.105949 DOI: https://doi.org/10.1016/j.porgcoat.2020.105949

K.A. Buyondo, H. Kasedde, J.B. Kirabira (2022) A comprehensive review on kaolin as pigment for paint and coating: Recent trends of chemical-based paints, their environmental impacts and regulation, Case Stud. Chem. Environ. Eng., 6, 100244. https://doi.org/10.1016/j.cscee.2022.100244 DOI: https://doi.org/10.1016/j.cscee.2022.100244

D. Hradil, J. Hradilová, P. Bezdicka (2020) Clay minerals in European painting of the Mediaeval and Baroque periods, Minerals, 10(3), 255. https://doi.org/10.3390/min10030255 DOI: https://doi.org/10.3390/min10030255

B.T. Brooks (1952) Evidence of catalytic action in petroleum formation, Ind. Eng. Chem., 44(11), 2570-2577. https://doi.org/10.1021/ie50515a032 DOI: https://doi.org/10.1021/ie50515a032

S. Bloch, R.H. Lander, L. Bonnell (2002) Anomalously high porosity and permeability in deeply buried sandstone reservoirs: Origin and predictability, AAPG Bull., 86(2), 301-328. https://doi.org/10.1306/61EEDABC-173E-11D7-8645000102C1865D DOI: https://doi.org/10.1306/61EEDABC-173E-11D7-8645000102C1865D

M. Lee, J.L. Aronson, S.M. Savin (1985) K/Ar dating of time of gas emplacement in Rotliegendes sandstone, Netherlands, AAPG Bull., 69(9), 1381-1385. https://doi.org/10.1306/AD462C68-16F7-11D7-8645000102C1865D DOI: https://doi.org/10.1306/AD462C68-16F7-11D7-8645000102C1865D

J. Schoonmaker, F.T. Mackenzie, R.C. Speed (1986) Tectonic implications of illite/smectite diagenesis, Barbados accretionary prism, Clays Clay Miner., 34(4), 465-472. https://doi.org/10.1346/CCMN.1986.0340413 DOI: https://doi.org/10.1346/CCMN.1986.0340413

V.A. Drits, H. Lindgreen, B.A. Sakharov, H.J. Jakobsen, A.L. Salyn, L.G. Dainyak (2002) Tobelitization of smectite during oil generation in oil-source shales, Clays Clay Miner., 50(1), 82-98. https://doi.org/10.1346/000986002761002702 DOI: https://doi.org/10.1346/000986002761002702

S. Jiang (2012) Clay minerals from the perspective of oil and gas exploration, Clay Miner. Nat., 21-38.https://doi.org/10.5772/47790 DOI: https://doi.org/10.5772/47790

N.B. Singh (2022) Clays and clay minerals in the construction industry, Minerals, 12(3), 301.https://doi.org/10.3390/min12030301 DOI: https://doi.org/10.3390/min12030301

M. Ahmad, K. Rashid (2022) Novel approach to synthesize clay-based geopolymer brick: Optimizing molding pressure and precursors' proportioning, Constr. Build. Mater., 322, 126472. https://doi.org/10.1016/j.conbuildmat.2022.126472 DOI: https://doi.org/10.1016/j.conbuildmat.2022.126472

G.J. Churchman, W.P. Gates, B.K.G. Theng, G. Yuan (2006) Clays and clay minerals for pollution control, Dev. Clay Sci., 1, 625-675. https://doi.org/10.1016/S1572-4352(05)01020-2 DOI: https://doi.org/10.1016/S1572-4352(05)01020-2

B. Sarkar, R. Rusmin, U.C. Ugochukwu, R. Mukhopadhyay, K.M. Manjaiah (2019) Modified clay minerals for environmental applications, Modif. Clay Zeolite Nanocompos.Mater., 113-127. https://doi.org/10.1016/B978-0-12-814617-0.00003-7 DOI: https://doi.org/10.1016/B978-0-12-814617-0.00003-7

M.K. Uddin (2017) A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade, Chem. Eng. J., 308, 438-462. https://doi.org/10.1016/j.cej.2016.09.029 DOI: https://doi.org/10.1016/j.cej.2016.09.029

B.O. Otunola, O.O. Ololade (2020) A review on the application of clay minerals as heavy metal adsorbents for remediation purposes, Environ. Technol. Innov., 18, 100692. https://doi.org/10.1016/j.eti.2020.100692 DOI: https://doi.org/10.1016/j.eti.2020.100692

S. Barakan, V. Aghazadeh (2021) The advantage of clay mineral modification methods for enhancing adsorption efficiency in wastewater treatment: A review, Environ. Sci. Pollut. Res., 28(3), 2572-2599. https://doi.org/10.1007/s11356-020-10985-9 DOI: https://doi.org/10.1007/s11356-020-10985-9

E. Wierzbicka, K. Kušmierek, A. Šwiatkowski, I. Legocka (2022) Efficient Rhodamine B dye removal from water by acid- and organo-modified halloysites, Minerals, 12(3), 350. https://doi.org/10.3390/min12030350 DOI: https://doi.org/10.3390/min12030350

A.K. Dhar, H.A. Himu, M. Bhattacharjee, M.G. Mostufa, F. Parvin (2023) Insights on applications of bentonite clays for the removal of dyes and heavy metals from wastewater: A review, Environ. Sci. Pollut. Res., 30(3), 5440-5474. https://doi.org/10.1007/s11356-022-24277-x DOI: https://doi.org/10.1007/s11356-022-24277-x

N. Chouikhi, J.A. Cecilia, E. Vilarrasa-Garcia, S. Besghaier, M. Chlendi, F.I. Franco Duro, E. Rodriguez Castellon, M. Bagane (2019) CO2 adsorption of materials synthesized from clay minerals: A review, Minerals, 9(9), 514. https://doi.org/10.3390/min9090514 DOI: https://doi.org/10.3390/min9090514

E. Haque, M.M. Islam, E. Pourazadi, S. Sarkar, A.T. Harris, A.I. Minett, E. Yanmaz, S.M. Alshehri, Y. Ide, K.C.W. Wu, Y.V. Kaneti (2017) Boron-functionalized graphene oxide-organic frameworks for highly efficient CO2 capture, Chem. Asian J., 12(3), 283-288. https://doi.org/10.1002/asia.201601442 DOI: https://doi.org/10.1002/asia.201601442

K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R. Long (2012) Carbon dioxide capture in metal-organic frameworks, Chem. Rev., 112(2), 724-781. https://doi.org/10.1021/cr2003272 DOI: https://doi.org/10.1021/cr2003272

J.S. Loring, H.T. Schaef, R.V. Turcu, C.J. Thompson, Q.R. Miller, P.F. Martin, J. Hu, D.W. Hoyt, O. Qafoku, E.S. Ilton, A.R. Felmy (2012) In situ molecular spectroscopic evidence for CO2 intercalation into montmorillonite in supercritical carbon dioxide, Langmuir, 28(18), 7125-7128. https://doi.org/10.1021/la301136w DOI: https://doi.org/10.1021/la301136w

L. Michels, J.O. Fossum, Z. Rozynek, H. Hemmen, K. Rustenberg, P.A. Sobas, G.N. Kalantzopoulos, K.D. Knudsen, M. Janek, T.S. Plivelic, G.J. da Silva (2015) Intercalation and retention of carbon dioxide in a smectite clay promoted by interlayer cations, Sci. Rep., 5, 8775. https://doi.org/10.1038/srep08775 DOI: https://doi.org/10.1038/srep08775

H.K. Christenson (1993) Adhesion and surface energy of mica in air and water, J. Phys. Chem., 97(46), 12034-12041. https://doi.org/10.1021/j100148a032 DOI: https://doi.org/10.1021/j100148a032

J.A. Cecilia, E. Vilarrasa-Garcia, C.L. Cavalcante Jr., D.C.S. Azevedo, F. Franco, E. Rodriguez-Castellon (2018) Evaluation of two fibrous clay minerals (sepiolite and palygorskite) for CO2 capture, J. Environ. Chem. Eng., 6(4), 4573-4587. https://doi.org/10.1016/j.jece.2018.07.001 DOI: https://doi.org/10.1016/j.jece.2018.07.001

G. Gómez-Pozuelo, E.S. Sanz-Pérez, A. Arencibia, P. Pizarro, R. Sanz, D.P. Serrano (2019) CO2 adsorption on amine-functionalized clays, Microporous Mesoporous Mater., 282, 38-47. https://doi.org/10.1016/j.micromeso.2019.03.012 DOI: https://doi.org/10.1016/j.micromeso.2019.03.012

F. Franco, M. Pozo, J.A. Cecilia, M. Benítez-Guerrero, E. Pozo, J.M. Rubi (2014) Microwave assisted acid treatment of sepiolite: The role of composition and "crystallinity", Appl. Clay Sci., 102, 15-27. https://doi.org/10.1016/j.clay.2014.10.013 DOI: https://doi.org/10.1016/j.clay.2014.10.013

K.J. Shah, T. Imae (2016) Analytical investigation of specific adsorption kinetics of CO2 gas on dendrimer loaded in organoclays, Chem. Eng. J., 283, 1366-1373. https://doi.org/10.1016/j.cej.2015.08.113 DOI: https://doi.org/10.1016/j.cej.2015.08.113

K.J. Shah, T. Imae, M. Ujihara, S.J. Huang, P.H. Wu, S.B. Liu (2017) Poly(amido amine) dendrimer-incorporated organoclays as efficient adsorbents for capture of NH3 and CO2, Chem. Eng. J., 312, 118-125. https://doi.org/10.1016/j.cej.2016.11.125 DOI: https://doi.org/10.1016/j.cej.2016.11.125

D. Kibanova, M. Trejo, H. Destaillats, J. Cervini-Silva (2009) Synthesis of hectorite-TiO2 and kaolinite-TiO2 nanocomposites with photocatalytic activity for the degradation of model air pollutants, Appl. Clay Sci., 42(3-4), 563-568. https://doi.org/10.1016/j.clay.2008.03.009 DOI: https://doi.org/10.1016/j.clay.2008.03.009

E. Manova, P. Aranda, M.A. Martin-Luengo, S. Letaief, E. Ruiz-Hitzky (2010) New titania-clay nanostructured porous materials, Microporous Mesoporous Mater., 131(1-3), 252-260. https://doi.org/10.1016/j.micromeso.2009.12.031 DOI: https://doi.org/10.1016/j.micromeso.2009.12.031

B. Paul, W.N. Martens, R.L. Frost (2012) Immobilized anatase on clay mineral particles as a photocatalyst for herbicides degradation, Appl. Clay Sci., 57, 49-54. https://doi.org/10.1016/j.clay.2011.12.009 DOI: https://doi.org/10.1016/j.clay.2011.12.009

D. Papoulis, S. Komarneni, A. Nikolopoulou, P. Tsolis-Katagas, D. Panagiotaras, H.G. Kacandes, P. Zhang, S. Yin, T. Sato, H. Katsuki (2010) Palygorskite- and halloysite-TiO2 nanocomposites: Synthesis and photocatalytic activity, Appl. Clay Sci., 50(1), 118-124. https://doi.org/10.1016/j.clay.2010.07.013 DOI: https://doi.org/10.1016/j.clay.2010.07.013

P. Aranda, R. Kun, M.A. Martin-Luengo, S. Letaief, I. Dekány, E. Ruiz-Hitzky (2008) Titania-sepiolite nanocomposites prepared by a surfactant templating colloidal route, Chem. Mater., 20(1), 84-91. https://doi.org/10.1021/cm702251f DOI: https://doi.org/10.1021/cm702251f

M. Valášková, J. Tokarský, J. Pavlovský, T. Prostějovský, K. Kočí (2019) α-Fe2O3 nanoparticles/vermiculite clay material: Structural, optical and photocatalytic properties, Materials, 12(11), 1880. https://doi.org/10.3390/ma12111880 DOI: https://doi.org/10.3390/ma12111880

Y. Guo, W. Yu, J. Chen, X. Wang, B. Gao, G. Wang (2017) Ag3PO4/rectorite nanocomposites: Ultrasound-assisted preparation, characterization and enhancement of stability and visible-light photocatalytic activity, Ultrason. Sonochem., 34, 831-838. https://doi.org/10.1016/j.ultsonch.2016.07.017 DOI: https://doi.org/10.1016/j.ultsonch.2016.07.017

H. Peng, X. Liu, W. Tang, R. Ma (2017) Facile synthesis and characterization of ZnO nanoparticles grown on halloysite nanotubes for enhanced photocatalytic properties, Sci. Rep., 7, 2251. https://doi.org/10.1038/s41598-017-02501-w DOI: https://doi.org/10.1038/s41598-017-02501-w

Y. Guo, C. Li, Y. Guo, X. Wang, X. Li (2019) Ultrasonic-assisted synthesis of mesoporous g-C3N4/Na-bentonite composites and its application for efficient photocatalytic simultaneous removal of Cr(VI) and RhB, Colloids Surf. A, 578, 123624. https://doi.org/10.1016/j.colsurfa.2019.123624 DOI: https://doi.org/10.1016/j.colsurfa.2019.123624

M. Akkari, P. Aranda, A. Amara, E. Ruiz-Hitzky (2018) Clay-nanoarchitectures as photocatalysts by in situ assembly of ZnO nanoparticles and clay minerals, J. Nanosci. Nanotechnol., 18(1), 223-233. https://doi.org/10.1166/jnn.2018.14613 DOI: https://doi.org/10.1166/jnn.2018.14613

Y. Shi, Y. Hu, L. Zhang, Z. Yang, Q. Zhang, H. Cui, X. Zhu, J. Wang, J. Chen, K. Wang (2017) Palygorskite supported BiVO4 photocatalyst for tetracycline hydrochloride removal, Appl. Clay Sci., 137, 249-258. https://doi.org/10.1016/j.clay.2016.12.035 DOI: https://doi.org/10.1016/j.clay.2016.12.035

C. Huo, H. Yang (2013) Preparation and enhanced photocatalytic activity of Pd-CuO/palygorskite nanocomposites, Appl. Clay Sci., 74, 87-94. https://doi.org/10.1016/j.clay.2012.07.001 DOI: https://doi.org/10.1016/j.clay.2012.07.001

C. Belver, J. Bedia, J.J. Rodriguez (2017) Zr-doped TiO2 supported on delaminated clay materials for solar photocatalytic treatment of emerging pollutants, J. Hazard. Mater., 322, 233-242. https://doi.org/10.1016/j.jhazmat.2016.02.028 DOI: https://doi.org/10.1016/j.jhazmat.2016.02.028

C. Belver, C. Han, J.J. Rodriguez, D.D. Dionysiou (2017) Innovative W-doped titanium dioxide anchored on clay for photocatalytic removal of atrazine, Catal. Today, 280, 21-28. https://doi.org/10.1016/j.cattod.2016.04.029 DOI: https://doi.org/10.1016/j.cattod.2016.04.029

B. Caglar, E.K. Guner, K. Keles, K.V. Özdokur, O. Cubuk, F. Coldur, S. Caglar, C. Topcu, A. Tabak (2018) Fe3O4 nanoparticles decorated smectite nanocomposite: Characterization, photocatalytic and electrocatalytic activities, Solid State Sci., 83, 122-136. https://doi.org/10.1016/j.solidstatesciences.2018.07.013 DOI: https://doi.org/10.1016/j.solidstatesciences.2018.07.013

C. Zhang, X. Han, F. Wang, L. Wang, J. Liang (2021) A facile fabrication of ZnFe2O4/sepiolite composite with excellent photocatalytic performance on the removal of tetracycline hydrochloride, Front. Chem., 9, 736369. https://doi.org/10.3389/fchem.2021.736369 DOI: https://doi.org/10.3389/fchem.2021.736369

B. John, K.K. Naira, K.A. Krishnan (2023) Synthesis and application of a thiol functionalized clay for borewell water purification: Microchemical characteristics and adsorption studies, Chem. Eng. Res. Des., 190, 33-53. https://doi.org/10.1016/j.cherd.2022.11.054 DOI: https://doi.org/10.1016/j.cherd.2022.11.054

M. Ghadiri, W. Chrzanowski, W.H. Lee, R. Rohanizade (2014) Layered silicate clay functionalized with amino acids: Wound healing application, RSC Adv., 4(67), 35332-35343. https://doi.org/10.1039/C4RA05216A DOI: https://doi.org/10.1039/C4RA05216A

M. Hnamte, A.K. Pulikkal (2022) Clay-polymer nanocomposites for water and wastewater treatment: A comprehensive review, Chemosphere, 307, 135869. https://doi.org/10.1016/j.chemosphere.2022.135869 DOI: https://doi.org/10.1016/j.chemosphere.2022.135869

N. Worasith, B.A. Goodman (2023) Clay mineral products for improving environmental quality, Appl. Clay Sci., 242, 106980. https://doi.org/10.1016/j.clay.2023.106980 DOI: https://doi.org/10.1016/j.clay.2023.106980

M. Malovanyy, O. Blazhko, H. Sakalova, T. Vasylinych (2021) Ecological aspects of clay sorption materials usage in leather and fur production technologies, Mater. Sci. Forum, 1038, 276-281. https://doi.org/10.4028/www.scientific.net/MSF.1038.276 DOI: https://doi.org/10.4028/www.scientific.net/MSF.1038.276

G. Sanchez-Olivares, F. Calderas, L. Medina-Torres, A. Sanchez-Solis, A. Rivera-Gonzaga, O. Manero (2015) Clay minerals and clay mineral water dispersions-properties and applications, In: Clays, Clay Miner. Ceram.Mater.Based Clay Miner., IntechOpen. https://doi.org/10.5772/61588 DOI: https://doi.org/10.5772/61588

E.J. Serge, J.P. Alla, P.D.B. Belibi, K.J. Mbadeam, N.N. Fathima (2019) Clay/polymer nanocomposites as filler materials for leather, J. Clean. Prod., 237, 117837. https://doi.org/10.1016/j.jclepro.2019.117837 DOI: https://doi.org/10.1016/j.jclepro.2019.117837

Y. Zhou, A.M. Lachance, A.T. Smith, H. Cheng, Q. Liu, L. Sun (2019) Strategic design of clay-based multifunctional materials: From natural minerals to nanostructured membranes, Adv. Funct. Mater., 29(45), 1807611. https://doi.org/10.1002/adfm.201807611 DOI: https://doi.org/10.1002/adfm.201807611

F.J. CarriónFité (2009) The effect of bentonite microparticles in the washing of cotton fabric, In: 9th World Textile Conf. AUTEX 2009, 1180-1186.

Downloads

Published

18-12-2025

Issue

Section

Review Paper