Assessment of the effect of mixing polystyrene (PS) with sawdust (SD) on copyrolysis products
DOI:
https://doi.org/10.62638/ZasMat1124Keywords:
PS plastic, biomass, sawdust, co-pyrolysis, bio-oil.Abstract
The co-pyrolysis process between biomass and solid waste especially plastics has attracted significant attention in research studies as a means to enhance both the quantity and quality of bio-oil derived from biomass decomposition. In this research paper, the PS/SD co-pyrolysis was carried out for six different concentrations ranging from 0% to 100%, with increments of 20% PS, inside a small laboratory reactor at 450 C and a heating rate (HR) of 20.5 oC min-1. Results showed that an increase in the proportion of PS in the blend resulted in a higher bio-oil outcome. The highest bio-oil yield was recorded at the 80PSSD blend, indicating that co-pyrolysis had a positive effect on oil production in all mixtures. The most significant positive impact was observed at the 20PSSD blend, reaching [+11.54]. Conversely, gas production showed a negative effect, with gas quantities lower than expected for all mixtures, and the most significant negative impact was at 20PSSD, with a decrease of [-11.8]. As for char outcome, there was a minimal increase in its quantity, with the highest positive impact of charcoal observed at 80PSSD, reaching [+3.44]. Consequently, it can be observed that the quantity of char produced is not significantly affected by the co-blending process.
References
E.Abokyi, P.Appiah, F.Abokyi, E.F.Oteng ( 2019) Industrial growth and emissions of CO2 in Ghana: the role of financial development and fossil fuel consumption, Energy Reports, 5, 1339 – 1353. https://doi.org/10.1016/j.egyr.2019.09.002
A.Foley, Ab.Ghani Olabi (2017) Renewable energy technology developments, trends and policy implications that can underpin the drive for global climate change, Renewable and Sustainable Energy Reviews, 68(2), 1112-1114
https://doi.org/10.1016/j.rser.2016.12.065
A.H.Zulkafli, H.Hassan, M.Ahmad, A.Mohd Din, S. Wasli (2023) Co-pyrolysis of biomass and waste plastics for production of chemicals and liquid fuel: A review on the role of plastics and catalyst types, Arabian Journal of Chemistry, 16, 104389.
https://doi.org/10.1016/j.arabjc.2022.104389
Jh.M.Aberilla, Al.Gallego-Schmid, Ad.Azapagic (2019) Environmental sustainability of small-scale biomass power technologies for agricultural communities in developing countries, Renewable Energy, 141, 493-506. https://doi.org/10.1016/ j.renene.2019.04.036
H.Hassan, J.K.Lim, B.Hameed (2016) Recent progress on biomass co-pyrolysis conversion into high-quality bio-oil. Bioresour Technol,. 221, 645-655. https://doi.org/10.1016/j.biortech.2016.09.026
P.M.Gvero, S.Papuga, I.Mujanić, S.Vasković (2016) Pyrolysis as a key process in biomass combustion and thermochemical conversion, Therm. Sci., 20(4), 1209–1222. https://doi.org/10.2298/TSCI151129154G
M.Ch.Chiong, Ch.T.Chong, Jo-Han Ng, Su.Sh. Lam, M-Vu Tran, W. W. F. Chong, M. N. M. Jaafar, A. Valera-Medina ( 2018) Liquid biofuels production and emissions performance in gas turbines: A review, Energy Conversion and Management, 173, 640-658.
https://doi.org/10.1016/j.enconman.2018.07.082
E.E.Kwon, J.I.Oh, K.H.Kim (2015) Polycyclic aromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs) mitigation in the pyrolysis process of waste tires using CO2 as a reaction medium, J. Environ. Manage., 160, 306–311.
https://doi.org/10.1016/j.jenvman.2015.06.033
J.Chattopadhyay, T.S.Pathak, R.Srivastava, A.C. Singh (2016) Catalytic co-pyrolysis of paper biomass and plastic mixtures (HDPE (high density polyethylene), PP (polypropylene) and PET (polyethylene terephthalate)) and product analysis, Energy, 103, 513– 521. https://doi.org/10.1016/j.energy.2016.03.015
H.Stančin, M.Šafář, J.Růžičková, H.Mikulčić, H. Raclavská, X.Wang, N.Duić (2021) Co-pyrolysis and synergistic effect analysis of biomass sawdust and polystyrene mixtures for production of high-quality bio-oils, Process Safety and Environmental Protection, 145, 1-11. https://doi.org/10.1016/j.psep.2020.07.023
N.Déparrois, P.Singh, K.G.Burra, A.K.Gupta (2019) Syngas production from co-pyrolysis and co-gasification of polystyrene and paper with CO2, Appl Energy, 246, 1–10. https://doi.org/10.1016/j.apenergy.2019.04.013
B.Muneer, M.Zeeshan, S.Qaisar, M.Razzaq, H. Iftikhar (2019) Influence of in-situ and ex-situ HZSM-5 catalyst on co-pyrolysis of corn stalk and polystyrene with a focus on liquid yield and quality, J Clean Prod, 237, 117762. https://doi.org/10.1016/j.jclepro.2019.117762
O.Sanahuja-Parejo, A.Veses, M.V.Navarro, J.M. López, R.Murillo, M.S.Callén (2019) Drop-in biofuels from the co-pyrolysis of grape seeds and polystyrene, Chem Eng J, 377, 120246. https://doi.org/10.1016/j.cej.2018.10.183
K.P.Shadangi, K.Mohanty (2015) Co-pyrolysis of Karanja and Niger seeds with waste polystyrene to produce liquid fuel, Fuel, 153, 492–8. https://doi.org/10.1016/j.fuel.2015.03.017
D.Watkins, M.Nuruddin, M.Hosur, A.T.Narteh, S. Jeelani (2015) Extraction and characterization of lignin from different biomass resources, Journal of Materials Research and Technology, 4(1), 26-32. https://doi.org/10.1016/j.jmrt.2014.10.009
Z.Xiao, S.Wang, M.Luo, J.Cai (2022) Combustion characteristics and synergistic effects during co-combustion of lignite and lignocellulosic components under oxy-fuel condition, Fuel, 310, Part B, 122399. https://doi.org/10.1016/j.fuel.2021.122399
S.D.Anuar Sharuddin, F.Abnisa, W.M.A.W.Daud, M. Kheir eddine Aroua (2016) A review on pyrolysis of plastic wastes, Energy Conversion and Management, 115, 308–326. http://dx.doi.org/10.1016/j.enconman.2016.02.037
Q.V.Nguyen, Y.S.Choi, S.K.Choi, Y.W.Jeong, Y.Su Kwon (2019) Improvement of bio-crude oil properties via co-pyrolysis of pine sawdust and waste polystyrene foam, Journal of Environmental Management, 237, 24-29. https://doi.org/10.1016/j.jenvman.2019.02.039