Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes

Authors

  • Sushant Kumar Center for Solar Cells and Renewable Energy, School of Basic Sciences and Research, Sharda University, Greater Noida, Uttar Pradesh 201306, India Author https://orcid.org/0000-0002-9326-1132
  • Dr. Manoj K. Singh Energy Conversion & Storage Lab, Department of Applied Science & Humanities, Rajkiya Engineering College Banda, AKTU, Uttar Pradesh, India Author https://orcid.org/0000-0001-7006-290X
  • Muhd Zu Azhan Yahya Faculty of Defence Science and Technology, Universiti Pertahanan Nasional Malaysia (UPNM), Kuala Lumpur, Malaysia Author https://orcid.org/0000-0003-1129-0552
  • Ikhwan Syafiq Mohd Noor Ionic Materials and Energy Devices Laboratory, Physics Department, Faculty of Science, Universiti Putra Malaysia, UPM Serdang, Selangor Darul Ehsan, Malaysia Author https://orcid.org/0000-0003-0983-782X
  • Prof. Pramod K. Singh Center for Solar Cells and Renewable Energy, School of Basic Sciences and Research, Sharda University, Greater Noida, Uttar Pradesh 201306, India Author https://orcid.org/0000-0002-3155-6621

DOI:

https://doi.org/10.62638/ZasMat1050

Keywords:

Biodegradable polymers, Phytagel, Ionic liquid, 1-ethyl-3-methylimidazolium tricyanomethanide, Polymer electrolyte

Abstract

The present work is focused on the synthesis and detailed study of biopolymer phytagel and ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide (EMIm[TCM]) blended polymer electrolyte films for energy applications. Here, biopolymer phytagel-based polymeric films are synthesized with different concentrations of ionic liquid (EMIm[TCM]) using the solution cast technique. The synthesized films are characterized for their structural, electrochemical, and dielectric properties using different characterization tools i.e., XRD, FTIR, Electrochemical Impedance Spectroscopy, Linear Sweep Voltammetry, and Wagnor polarization technique. The film with 30wt% EMIm[TCM] shows a maximum conductivity of 3.64 × 10-4 S cm-1 and an electrochemical stability window of 3.1 V. The dielectric properties such as dielectric constant (κ), dielectric loss tangent (tanδ), relaxation time, and frequency are also studied for the prepared pure phytagel and phytagel/EMIm[TCM] polymeric films.

References

A.Rajapriya, S.Keerthana, N.Ponpandian (2023) Fundamental understanding of charge storage mechanism. In: Smart Supercapacitors. Elsevier, p. 65–82. https://doi.org/10.1016/B978-0-323-90530-5.00034-4

L.Xia, L.Yu, D.Hu, et al. (2017) Electrolytes for electrochemical energy storage. Materials Chemistry Frontiers, 1, 584–618. https://doi.org/10.1039/C6QM00169F

A.Singh, P.S.Dhapola, S.Kumar, et al. (2022) Highly conducting ionic liquid doped polymer electrolyte for energy storage applications. Journal of Science: Advanced Materials and Devices, 7, 100511. https://doi.org/10.1016/j.jsamd.2022.100511.

G-R.Zhu, Q.Zhang, Q-S.Liu, et al. (2023) Non-flammable solvent-free liquid polymer electrolyte for lithium metal batteries. Nat Commun, 14, 4617. https://doi.org/10.1038/s41467-023-40394-8.

S.B.Aziz, O.G.Abdullah, R.T.Abdulwahid, et al. (2023) EDLC performance of plasticized NBG electrolyte inserted with Ba (NO3) 2 salt: Impedance, electrical and electrochemical properties. Electrochimica Acta, 467, 143134. https://doi.org/10.1016/j.electacta.2023.143134

H.Niu, M.Ding, N.Zhang, et al. (2023) Preparation of imidazolium based polymerized ionic liquids gel polymer electrolytes for high-performance lithium batteries. Materials Chemistry and Physics, 293, 126971. https://doi.org/10.1016/j.matchemphys.2022.126971

P.Rawat, A.L.Saroj. (2023) Effect of ionic liquid on plasticized CS-PVP-NaI based bio-polymer blend electrolytes: Structural, thermal, dielectric and ion transport properties study. Materials Science and Engineering: B, 288, 116215. https://doi.org/10.1016/j.mseb.2022.116215

S.Kumari, A.Rao, M.Kaur, et al. (2023) Petroleum-Based Plastics Versus Bio-Based Plastics: A Review. Nature Environment & Pollution Technology, 22. https://doi.org/10.46488/NEPT.2023.v22i03.003

S.Konwar, P.K.Singh, P.Dhapola, et al. (2023) Developing Biopolymer-Based Electrolytes for Supercapacitor and Dye-Sensitized Solar Cell Applications. ACS Applied Electronic Materials, 5, 5503–5512. https://doi.org/10.1021/acsaelm.3c00736

R.T.Abdulwahid, S.B.Aziz, M.F.Z.Kadir. (2023) Replacing synthetic polymer electrolytes in energy storage with flexible biodegradable alternatives: sustainable green biopolymer blend electrolyte for supercapacitor device. Materials Today Sustainability, 23, 100472. https://doi.org/10.1016/j.mtsust.2023.100472

M. Kani Ajay Babu, S.S.Jayabalakrishnan, S.Selvasekarapandian, et al. (2023) Development and characterization of biopolymer electrolyte based on gellan gum for the fabrication of solid-state sodium-ion battery. Ionics, 29, 5249–5265. https://doi.org/10.1007/s11581-023-05210-9

J.L.Shamshina, P.Berton. (2023) Renewable biopolymers combined with ionic liquids for the next generation of supercapacitor materials. International Journal of Molecular Sciences, 24, 7866. https://doi.org/10.3390/ijms24097866

M.S.A.Rani, N.S.Isa, N.M.Nurazzi, et al. (2023) Effect of SiO2 ceramic filler on carboxymethyl cellulose from palm oil empty fruit bunch-based nanocomposite biopolymer electrolyte. In: Synthetic and Natural Nanofillers in Polymer Composites. Elsevier, pp. 127–139. https://doi.org/10.1016/B978-0-443-19053-7.00022-6

F.C.Tavares, C.M.Cholant, E.C.Kohlrausch, et al. (2023) Ionic liquid boosted conductivity of biopolymer gel electrolyte. Journal of the Electrochemical Society, 170, 084501. https://doi.org/10.1149/1945-7111/ace937

M.J.Park, I.Choi, J.Hong, et al. (2013) Polymer electrolytes integrated with ionic liquids for future electrochemical devices. J of Applied Polymer Sci, 129, 2363–2376. https://doi.org/10.1002/app.39064

G.A.Tiruye, D.Muñoz-Torrero, J.Palma, et al. (2016) Performance of solid state supercapacitors based on polymer electrolytes containing different ionic liquids. Journal of Power Sources, 326, 560–568. https://doi.org/10.1016/j.jpowsour.2016.03.044

A.S.F.M.Asnawi, M.H.Hamsan, S.B.Aziz, et al. (2021) Impregnation of [Emim]Br ionic liquid as plasticizer in biopolymer electrolytes for EDLC application. Electrochimica Acta, 375, 137923. https://doi.org/10.1016/j.electacta.2021.137923

S.Romano, S.De Santis, A.Martinelli, et al. (2023) Starch films plasticized by imidazolium-based ionic liquids: Effect of mono-and dicationic structures and different anions. ACS Applied Polymer Materials, 5, 8859–8868. https://doi.org/10.1021/acsapm.3c01235

S.Konwar, A.Singh, P.K.Singh, et al. (2023) Highly conducting corn starch doped ionic liquid solid polymer electrolyte for energy storage devices. High Performance Polymers, 35, 63–70. https://doi.org/10.1021/acsapm.3c01235

C.Naveen, M.Muthuvinayagam. (2023) Studies on electrical properties of Chitosan-PVA based biopolymer electrolytes for electrochemical devices. Journal of Polymer Research, 30, 353. https://doi.org/10.1007/s10965-023-03741-3

S.Sowmiyaa, C.Shanthia, S.Selvasekarapandianb. (2023) Development of sodium-ion conducting biopolymer electrolyte membrane based on Agar-Agar with sodium perchlorate (NaClO4) using ethylene carbonate (EC) as a plasticizer for primary Na-ion battery. DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 18, 1537–1555. https://doi.org/10.15251/DJNB.2023.184.1537

P.S.Rudati, Y.Dzakiyyah, R.Fane, et al. (2023) Biopolymer Kappa Carrageenan with Ammonium Chloride as Electrolyte for Potential Application in Organic Battery. Key Engineering Materials, 950, 11–16. https://doi.org/10.4028/p-FW7xiu

M.Kani Ajay Babu, S.S.Jayabalakrishnan, S.Selvasekarapandian, et al. (2023) Development and characterization of biopolymer electrolyte based on gellan gum for the fabrication of solid-state sodium-ion battery. Ionics, 29, 5249–5265. https://doi.org/10.1007/s11581-023-05210-9

S.Eswaragomathy, S.Selvanayagam, S.Selvasekarapandian, et al. (2023) Preparation of pectin biopolymer electrolyte for zinc-ion battery application. Ionics, 29, 2329–2340. https://doi.org/10.1007/s11581-023-05005-y

D.Singh, S.Kumar, A.Singh, et al. (2022) Ionic liquid–biopolymer electrolyte for electrochemical devices. Ionics, 28, 759–766. https://doi.org/10.1007/s11581-021-04372-8

K.Karuppasamy, D.Vikraman, K.Jang, et al. (2021) Bio‐inspired proton conducting phytagel derived zwitterionic complex membranes for fuel cells. Intl J of Energy Research, 45, 17120–17132. https://doi.org/10.1002/er.5386

X.Wu, A.Surendran, J.Ko, et al. (2019) Ionic‐Liquid Doping Enables High Transconductance, Fast Response Time, and High Ion Sensitivity in Organic Electrochemical Transistors. Advanced Materials, 31, 1805544. https://doi.org/10.1002/adma.201805544

S.Kumar, P.K.Singh, D.Agarwal, et al. (2022) Structure, Dielectric, and Electrochemical Studies on Poly(Vinylidene Fluoride‐Co‐Hexafluoropropylene)/IonicLiquid 1‐Ethyl‐3‐Methylimidazolium Tricyanomethanide‐Based Polymer Electrolytes. Physica Status Solidi (a), 219, 2100711. https://doi.org/10.1002/pssa.202100711

R.Singh, B.Bhattacharya, H-W.Rhee, et al. (2015) Solid gellan gum polymer electrolyte for energy application. International Journal of Hydrogen Energy, 40, 9365–9372. https://doi.org/10.1016/j.ijhydene.2015.05.084

G.Nath, P.S.Dhapola, N.Sahoo, et al. (2022) Polyvinylpyrrolidone with ammonium iodide and plasticizer ethylene carbonate solid polymer electrolyte for supercapacitor application. Journal of Thermoplastic Composite Materials, 35, 879–890. https://doi.org/10.1177/0892705720925115

D.Kumar, K.Gohel, D.K.Kanchan, et al. (2020) Dielectrics and battery studies on flexible nanocomposite gel polymer electrolyte membranes for sodium batteries. Journal of Materials Science: Materials in Electronics, 31, 13249–13260. https://doi.org/10.1007/s10854-020-03877-8

Downloads

Published

15-12-2024

Issue

Vol. 65 No. 4 (2024)

Section

Scientific paper

License

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.