Electrochemical analysis of corrosion inhibition shallot leaf (Allium cepa) extract on mild steel in acidic medium at different immersion times
DOI:
https://doi.org/10.62638/ZasMat1006Keywords:
Corrosion inhibitor, plant extract, shallot leaf extract, carbon steel, immersion timeAbstract
Plant derivatives as eco-friendly corrosion inhibitors are currently greatly interested in much research. Shallot leaf (Allium cepa) was utilized in 0.1M HCl as a corrosion inhibitor of mild steel. The functional groups present in the macerated extract were subsequently identified using an FTIR test. Electrochemical tests such as tafel polarization and EIS were carried out to determine the corrosion inhibition performance of shallot leaf extract on the SS400 steel. The results of the electrochemical analysis show that shallot leaf extract can inhibit mild steel up to 94% at a concentration of 500 ppm. Furthermore, the addition of SLE reduces surface damage of mild steel, which can be seen by SEM.
References
X.Joy Pradeep, J.Sathiyabama (2021) A study on corrosion inhibition of Carbon steel in well water by Oxalis corniculata L. Leaves extract, Mater. Today. Proc., 47, 154-158.
https://doi.org/10.1016/j.matpr.2021.04.031
M.Finšgar, J.Jackson (2014) Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review, Corros. Sci., 86, 17-41.
https://doi.org/10.1016/j.corsci.2014.04.044
X.Zuo, W. Li, W.Luo, X.Zhang, Y. Qiang, J.Zhang, H.Li, B.Tan (2021) Research of Lilium brownii leaves extract as a commendable and green inhibitor for X70 steel corrosion in hydrochloric acid, J. Mol. Liq., 321 114914.
https://doi.org/10.1016/j.molliq.2020.114914
C.G.Dariva, A.F.Galio (2016) Corrosion inhibitors: Principles, mechanisms and applications, in: M. Aliofkhazraei (Ed.), Developments in Corrosion Protection, Intech Open, book, p.365-379.
N.Chaubey, P.Savita, A.Qurashi, D.S.Chauhan, M.A.Quraishi (2021) Frontiers and advances in green and sustainable inhibitors for corrosion applications: A critical review, J. Mol. Liq., 321, 115085.
https://doi.org/10.1016/j.molliq.2020.114385
S.Chitra, I.M.Chung, S.H.Kim, M.Prabakaran (2019) A study on anticorrosive property of phenolic components from Pachysandra terminalis against low carbon steel corrosion in acidic medium, Pigment. Resin. Technol., 48, 389-396.
https://doi.org/10.1108/PRT-09-2018-0095
D.Lakshmi, S.Rajendran, J.Sathiyabama (2016) Corrosion Inhibition by Phenols - An Overview, Int. j. nano corros. sci. eng., 3, 1-18.
A.P.S.Kaban, A.Ridhova, G.Priyotomo, B.Elya, A. Maksum, Y.Sadeli, T.Aditiyawarman, R.Riastuti, J.W.Soedarsono (2021) Development of White Tea Extract As Green Corrosion Inhibitor in Mild Steel Under 1 M Hydrochloric Acid Solution, East. -Eur. J. Enterp., 2, 6-20.
https://doi.org/10.15587/1729-4061.2021.224435
A.A.Olajire (2017) Corrosion inhibition of offshore oil and gas production facilities using organic compound inhibitors - A review, J. Mol. Liq., 248, 775-808.
https://doi.org/10.1016/j.molliq.2017.10.097
E. de B.Policarpi, A.Spinelli (2020) Application of Hymenaea stigonocarpa fruit shell extract as eco-friendly corrosion inhibitor for steel in sulfuric acid, J. Taiwan. Inst. Chem. Eng., 116, 215-222.
https://doi.org/10.1016/j.jtice.2020.10.024
A.A.Khadom, A.N.Abd, N.A.Ahmed (2018) Xanthium strumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: Kinetics and mathematical studies, S. Afr. J. Chem. Eng., 25, 13-21.
https://doi.org/10.1016/j.sajce.2017.11.002
E.Honarmand, H.Mostaanzadeh, M.H. Motaghedifard, M.Hadi, M.Khayadkashani (2017) Inhibition effect of opuntia stem extract on corrosion of mild steel: a quantum computational assisted electrochemical study to determine the most effective components in inhibition, Prot. Met. Phys. Chem., 53, 560-572.
https://doi.org/10.1134/S207020511703008X
A.Dehghani, G.Bahlakeh, B.Ramezanzadeh, M. Ramezanzadeh (2019) Potential of Borage flower aqueous extract as an environmentally sustainable corrosion inhibitor for acid corrosion of mild steel: Electrochemical and theoretical studies, J. Mol. Liq., 277, 895-911.
https://doi.org/10.1016/j.molliq.2019.01.008
A.Rajendran, C.Karthikeyan (2012) The Inhibitive Effect of Extract of Flowers of Cassia Auriculata in 2 M HCl on the Corrosion of Aluminium and Mild Steel, Int. J. Plant Res. 2, 9-14.
https://doi.org/10.5923/j.plant.20120201.02
H.Hassannejad (2018) A. Nouri, Sunflower seed hull extract as a novel green corrosion inhibitor for mild steel in HCl solution, J. Mol. Liq., 254, 377-382.
https://doi.org/10.1016/j.molliq.2018.01.142
L.L.Liao, S.Mo, H.Q.Luo, N.B.Li (2018) Corrosion protection for mild steel by extract from the waste of lychee fruit in HCl solution: Experimental and theoretical studies, J. Colloid. Interface. Sci., 520, 41-49.
https://doi.org/10.1016/j.jcis.2018.02.071
N.Marefati, N.Eftekhar, M.Kaveh, J.Boskabadi, F. Beheshti, M.H.Boskabady (2018) The Effect of Allium cepa Extract on Lung Oxidant, Antioxidant, and Immunological Biomarkers in Ovalbumin-Sensitized Rats, Med. Princ. Pract.., 27, 122-128.
https://doi.org/10.1159/000487885
S.Masood, A.Rehman, M.A.Ihsan, K.Shahzad, M. Sabir, S.Alam, W.Ahmed, Z.H.Shah, F.Alghabari, A. Mehmood, G.Chung (2023) Antioxidant potential and α-glucosidase inhibitory activity of onion (Allium cepa L.) peel and bulb extracts, Braz. J. Biol., 83, 1-9.
https://doi.org/10.1590/1519-6984.247168
V. Lanzotti (2006) The analysis of onion and garlic, J. Chromatogr. A., 1112, 3-22. doi: 10.1016/ J. CHROMA.2005.12.016.
https://doi.org/10.1016/j.chroma.2005.12.016
K.H.Miean, S.Mohamed (2001) Flavonoid (myricetin, quercetin, kaempferol, luteolin, and apigenin) content of edible tropical plants, J. Agric. Food. Chem., 49, 3106-3112.
https://doi.org/10.1021/jf000892m
A.A.Rahim, E.Rocca, J.Steinmetz, M.J.Kassim, R. Adnan, M.Sani Ibrahim (2007) Mangrove tannins and their flavanoid monomers as alternative steel corrosion inhibitors in acidic medium, Corros. Sci., 49, 402-417.
https://doi.org/10.1016/j.corsci.2006.04.013
K.W.Tan, M.J.Kassim (2011) A correlation study on the phenolic profiles and corrosion inhibition properties of mangrove tannins (Rhizophora apiculata) as affected by extraction solvents, Corros. Sci., 53, 569-574.
https://doi.org/10.1016/j.corsci.2010.09.065
A.B.D.Nandiyanto, R.Oktiani, R.Ragadhita (2019) How to read and interpret ftir spectroscope of organic material, Indones. J. Sci. Technol., 4, 97-118.
https://doi.org/10.17509/ijost.v4i1.15806
N. el Hamdani, R.Fdil, M.Tourabi, C.Jama, F. Bentiss (2015) Alkaloids extract of Retama monosperma (L.) Boiss. seeds used as novel eco-friendly inhibitor for carbon steel corrosion in 1 M HCl solution: Electrochemical and surface studies, Appl. Surf. Sci., 357, 1294-1305.
https://doi.org/10.1016/j.apsusc.2015.09.159
M.Ramezanzadeh, G.Bahlakeh, Z.Sanaei, B. Ramezanzadeh (2019) Corrosion inhibition of mild steel in 1 M HCl solution by ethanolic extract of eco-friendly Mangifera indica (mango) leaves: Electrochemical, molecular dynamics, Monte Carlo and ab initio study,Appl.Surf. Sci., 463, 1058-1077.
https://doi.org/10.1016/j.apsusc.2018.09.029
P.E.Alvarez, M.V.Fiori-Bimbi, A.Neske, S.A. Brandán, C.A.Gervasi (2018) Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution, J. Ind. Eng. Chem., 58, 92-99.
https://doi.org/10.1016/j.jiec.2017.09.012
S.Kadapparambil, K.Yadav, M.Ramachandran, N. Vi.Selvam (2017) Electrochemical investigation of the corrosion inhibition mechanism of Tectona grandis leaf extract for SS304 stainless steel in hydrochloric acid, Corros., 35. 111-121.
https://doi.org/10.1515/corrrev-2016-0074
J.P.Flores-De Los Ríos, M.Sánchez-Carrillo, C.G. Nava-Dino, J.G.Chacón-Nava, J.G.González-Rodríguez, E.Huape-Padilla, M.A.Neri-Flores, A. Martínez-Villafañe (2015) Opuntia ficus-indica extract as green corrosion inhibitor for carbon steel in 1M HCl solution, J. Spectrosc., 2015, ID 714692.
https://doi.org/10.1155/2015/714692
A.Sedik, D.Lerari, A.Salci, S.Athmani, K.Bachari, H. Gecibesler, R.Solmaz (2020) Dardagan Fruit extract as eco-friendly corrosion inhibitor for mild steel in 1 M HCl: Electrochemical and surface morphological studies, J. Taiwan. Inst. Chem. Eng., 107, 189-200.
https://doi.org/10.1016/j.jtice.2019.12.006
A.Dehghani, G.Bahlakeh, B.Ramezanzadeh, M. Ramezanzadeh (2019) Potential of Borage flower aqueous extract as an environmentally sustainable corrosion inhibitor for acid corrosion of mild steel: Electrochemical and theoretical studies, J. Mol. Liq., 277, 895-911.
https://doi.org/10.1016/j.molliq.2019.01.008
J.Aldana-González, A.Espinoza-Vázquez, M. Romero-Romo, J.Uruchurtu-Chavarin, M.Palomar-Pardavé (2019) Electrochemical evaluation of cephalothin as corrosion inhibitor for API 5L X52 steel immersed in an acid medium, Arab. J. Chem., 12, 3244-3253.
https://doi.org/10.1016/j.arabjc.2015.08.033
R.Riastuti, G. Mashanafie, V.Rizkia, A.Maksum, S. Prifiharni, A.Kaban, G.Priyotomo, J.Soedarsono (2022) Effect of syzygium cumini leaf extract as a green corrosion inhibitor on API 5l carbon steel in 1M HCL, East. -Eur. J. Enterp., 6, 30-41.
https://doi.org/10.15587/1729-4061.2022.267232
Z.Sanaei, M.Ramezanzadeh, G.Bahlakeh, B. Ramezanzadeh (2019) Use of Rosa canina fruit extract as a green corrosion inhibitor for mild steel in 1 M HCl solution: A complementary experimental, molecular dynamics and quantum mechanics investigation, J. Ind. Eng. Chem., 69, 18-31.
https://doi.org/10.1016/j.jiec.2018.09.013
M.T.Majd, M.Ramezanzadeh, B.Ramezanzadeh, G. Bahlakeh (2020) Production of an environmentally stable anti-corrosion film based on Esfand seed extract molecules-metal cations: Integrated experimental and computer modeling approaches, J. Hazard. Mater., 382, 121029.
https://doi.org/10.1016/j.jhazmat.2019.121029
[H.L.Y.Sin, A. Abdul Rahim, C.Y.Gan, B.Saad, M.I. Salleh, M.Umeda (2017) Aquilaria subintergra leaves extracts as sustainable mild steel corrosion inhibitors in HCl, Measurement., 109, 334-345.
https://doi.org/10.1016/j.measurement.2017.05.045
A. R. Shahmoradi, M. Ranjbarghanei, A. A. Javidparvar, L. Guo, E. Berdimurodov, B. Ramezanzadeh (2021) Theoretical and surface/electrochemical investigations of walnut fruit green husk extract as effective inhibitor for mild-steel corrosion in 1M HCl electrolyte, J. Mol. Liq., 338, 116550.
https://doi.org/10.1016/j.molliq.2021.116550
Q.Wang, H.Zheng, L. Liu, Q. Zhang, X. Wu, Z.Yan, Y.Sun, X. Li (2022) Insight into the anti-corrosion behavior of Reineckia Carnea leaves extract as an eco-friendly and high-efficiency corrosion inhibitor, Ind. Crops. Prod., 188 A, 115752.
https://doi.org/10.1016/j.indcrop.2022.115640
B. Liao, Z. Luo, S. Wan, L. Chen (2023) Insight into the anti-corrosion performance of Acanthopanax senticosus leaf extract as eco-friendly corrosion inhibitor for carbon steel in acidic medium, J. Ind. Eng. Chem., 117, 238-246.
